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Chemical Sampling Information (CSI)
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General Description

Synonyms: Aluminum; Aluminium; Aluminum powder; Aluminum, elemental

OSHA IMIS Code Number: A100

Chemical Abstracts Service (CAS) Registry Number: 7429-90-5

NIOSH Registry of Toxic Effects of Chemical Substances (RTECS) Identification Number: BD0330000

Department of Transportation Regulation Number (49 CFR 172.101) and 2012 Emergency Response Guidebook [4 MB PDF, 392 pages]: 1309 170 (powder, coated); 1396 138 (powder, uncoated); 9260 169 (molten)

NIOSH Pocket Guide to Chemical Hazards - Aluminum: Physical description, chemical properties, potentially hazardous incompatibilities, and more


Exposure Limits and Health Effects

Exposure Limit

Limit Values

HE Codes

Health Factors and Target Organs

OSHA Permissible Exposure Limit (PEL) - General Industry
See 29 CFR 1910.1000 Table Z-1

15 mg/m3 TWA

HE19

 

Physical irritation*

 

OSHA PEL - Construction Industry

Not established

 

 

OSHA PEL - Shipyard Employment
See 29 CFR 1915.1000 Table Z-Shipyards

15 mg/m3 TWA

HE19

Physical irritation*

National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL)

10 mg/m3 TWA

HE10

Lung changes that may lead to pulmonary fibrosis

American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) (2008)

Not established

 

 

CAL/OSHA PEL 10 mg/m3 TWA

 

 

*Health factors for the PELs are not specific to aluminum but are the basis for OSHA's generic limits for particulates.

National Toxicology Program (NTP) carcinogenic classification: Not listed

International Agency for Research on Cancer (IARC): Not listed

U.S. Environmental Protection Agency (EPA) carcinogenic classification: Not listed

EPA Inhalation Reference Concentration (RfC): Not established

Agency for Toxic Substances and Disease Registry (ATSDR) Inhalation Minimal Risk Level (MRL): Not established

NIOSH Immediately Dangerous to Life or Health (IDLH) concentration: Not listed

Notes on Other Potential Health Effects and Hazards

  1. Respiratory effects, particularly impaired lung function and fibrosis, have been observed in workers exposed to aluminum dust or fumes (ATSDR 2008).
  2. Aluminium cast-house workers reported significantly more respiratory symptoms (continuous trouble with breathing, repeated trouble with breathing, wheezing, asthma attacks, and doctor-diagnosed asthma) compared to a general population sample and an internal reference group (van Rooy et al. 2011).
  3. Chronic occupational exposure to aluminum dust and fumes can cause signs of cholestasis (Bogdanovic and Bulat 2008).

Literature Basis

  • ACGIH: Documentation of the Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) - Aluminum Metal and Insoluble Compounds. 2008.
  • ATSDR: Toxicological Profile for Aluminum. September 2008.
  • Bogdanovic, M. and Bulat, P.: Biliary Function in Workers Occupationally Exposed to Aluminum Dust and Fumes. Archives of Industrial Hygiene and Toxicology 59(2): 135-9, 2008.
  • NIOSH: Recommendations for occupational safety and health - Compendium of policy documents and statements. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health, DHHS (NIOSH) Publication No. 92-100. 1992.
  • NIOSH: Occupational Health Guidelines for Chemical Hazards. US Department of Health and Human Services (DHHS), National Institute for Occupational Safety and Health (NIOSH) Publication No. 81-123, (1981, January). Provides a table of contents of guidelines for many hazardous chemicals. The files provide technical chemical information, including chemical and physical properties, health effects, exposure limits, and recommendations for medical monitoring, personal protective equipment (PPE), and control procedures.
  • van Rooy, F.G., Houba, R., Stigter, H., Zaat, V.A., Zengeni, M.M., Rooyackers, J.M., Boers, H.E., Heederik, D.J.: A cross-sectional study of exposures, lung function and respiratory symptoms among aluminium cast-house workers. Occup Environ Med. 68(12): 876-82, 2011.

Date last revised: 09/06/2012

Monitoring Methods used by OSHA

Laboratory Sampling/Analytical Method:

Federal OSHA and OSHA State Plan personnel submitting samples to the OSHA Salt Lake Technical Center Laboratory for analysis must use the tared gravimetric sampling media described immediately below.
  • sampling media: tared 37-mm diameter low-ash polyvinyl chloride filter
    maximum volume: 960 Liters
    minimum volume: 480 Liters
    maximum flow rate: 2.0 L/min
    current analytical method: Gravimetric
    method reference: OSHA Analytical Method (OSHA PV2121)
    method classification: Partially Validated
    note: OSHA personnel can obtain tared sampling media from the Salt Lake Technical Center.
    note: If the net weight of the sample yields a concentration below the standard for the substance, the Salt Lake Technical Center will perform no further work on that sample. If the net weight corresponds to an amount greater than the standard, the sample may be analyzed for the appropriate element and the result reported as the substance.
    note: Refer to Chemical Sampling Information for "alpha-Alumina" when sampling workplaces that have aluminum oxide exposures (welding, etc.).
    current elemental analysis method: Atomic Absorption Spectroscopy; AAS
    method reference: OSHA Analytical Method (OSHA ID-121)
    method classification: Fully Validated
    alternate analytical method: Samples are prepared as described in OSHA ID-121 and are analyzed by Inductively Coupled Argon Plasma; ICP/AES or ICP/MS.
    note: When analysis of aluminum metal is requested, an elemental analysis is performed and reported as aluminum metal. The analytical method does not distinguish between dust and fume; or between aluminum metal and other acid soluble or partially acid soluble aluminum compounds.
Alternative Sampling/Analytical Method:
  • sampling media: Mixed Cellulose Ester Filter (MCEF) 0.8 m
    maximum volume: 960 Liters
    minimum volume: 480 Liters
    maximum flow rate: 2.0 L/min
    current elemental analysis method: Atomic Absorption Spectroscopy; AAS
    method reference: OSHA Analytical Method (OSHA ID-121)
    method classification: Fully Validated
    alternate analytical method: Samples are prepared as described in OSHA ID-121 and are analyzed by Inductively Coupled Argon Plasma; ICP/AES or ICP/MS.
    note: When analysis of aluminum metal is requested, an elemental analysis is performed and reported as aluminum metal. The analytical method does not distinguish between dust and fume; or between aluminum metal and other acid soluble or partially acid soluble aluminum compounds.

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