BERYLLIUM & COMPOUNDS (as Be)‡
| CAS # | 7440-41-7 |
|---|---|
| Formula |
Be |
| Synonyms |
Synonyms vary depending upon the specific beryllium compound. |
| Physical description | hard, brittle, gray-white solid, metal | ||
|---|---|---|---|
| Boiling point | 4532°F | Molecular weight | 9.0 |
| Freezing point/melting point | 2349°F | Vapor pressure | 0 mmHg (approx) |
| Flash point | Vapor density | ||
| Specific gravity | 1.85 (metal) | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | 2349°F | |
| NFPA health rating | 3 | NFPA fire rating | 1 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 0365 (high sensitivity) |
|---|---|
| Sampling group | |
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) [MAWP037A0] |
| Sampling time* | 240 min |
| Sampling volume (TWA)* | 480 L |
| Sampling flow rate (TWA)* | 2 L/min |
| Sampling volume (STEL/Peak/C)* | 30 L |
| Sampling flow rate (STEL/Peak/C)* | 2 L/min |
| Analytical method instruments | ICP-AES |
| Method reference | OSHA 1023 (fully validated) |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. |
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with Whatman smear tab. [WHA1450993] |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.2 µg/m³ [0.1 µg/m³ Action Level] |
REL-TWA | TLV-TWA | PEL-TWA |
0.0002 mg/m³ |
||
| PEL-STEL |
2 µg/m³ |
REL-STEL | TLV-STEL | PEL-STEL |
0.002 mg/m³ |
||
| PEL-C | REL-C | TLV-C | PEL-C |
0.025 mg/m³ |
|||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
Y |
Skin notation |
N |
|
Notes:
See 29 CFR 1910.1024, Beryllium. See 29 CFR 1910.1000 Table Z-2for any operations or sectors where the exposure limits in 1910.1024 are stayed or otherwise not in effect. |
Notes:
CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens |
Notes:
Visit the ACGIH TLV site for specific data |
Notes:
See also California Code of Regulations, Title 8 §1535.1 Beryllium., §5205. Beryllium., and §8359.1 Beryllium. |
||||
| Health factors: See NIH-NLM PubChem. | IDLH |
4 mg/m³ |
|||||
| Carcinogenic classifications: IARC-1, NIOSH-Ca, NTP-K, TLV-A1, EPA-B1; L; CBD |
Notes:
Ca |
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
--/0.025 mg/m³/0.1 mg/m³ |
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Beryllium compound, N.O.S. NIOSH: Pocket Guide to Chemical Hazards - Beryllium and beryllium compounds (as Be) Literature References
|
Last Updated Date : 03/27/2024
BARIUM, SOLUBLE COMPOUNDS (EXCEPT BARIUM SULFATE)†
| CAS # | 7440-39-3 |
|---|---|
| Formula |
Ba |
| Synonyms |
Synonyms vary depending upon the specific soluble barium compound. |
| Physical description | A silver to white metallic, odorless solid | ||
|---|---|---|---|
| Boiling point | 2984°F | Molecular weight | 137.33 |
| Freezing point/melting point | 1337°F | Vapor pressure | 10 mmHg at 1920°F |
| Flash point | Vapor density | ||
| Specific gravity | 3.51 at 68°F | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 0310 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | Tared low-ash 37 mm PVC filter, 5 microns [SLTC108] |
| Sampling time* | 240-480 min |
| Sampling volume (TWA)* | 480-960 L |
| Sampling flow rate (TWA)* | 2 L/min |
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | Gravimetric |
| Method reference | OSHA PV2121 (partially validated) |
| Notes | Samples are first analyzed gravimetrically. If the gravimetric result of a sample yields a concentration below the permissible exposure limit (PEL), the SLTC will report the calculated air concentration from the gravimetric result, qualified as less than or equal to the gravimetric result; no further work on the sample will be performed. If the gravimetric result indicates an air concentration greater than the PEL, the sample will proceed for elemental analysis. Results will be reported from the elemental analysis for the element only; the stated identity of the actual sample contents is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. Analysis for this analyte is based on water solubility. |
| Special requirements | FOR TOTAL DUST SAMPLES, DO NOT USE A CYCLONE!! |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with Whatman smear tab. [WHA1450993] |
|---|---|
| Bulk Method |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.5 mg/m³ |
REL-TWA |
0.5 mg/m³ |
TLV-TWA | PEL-TWA |
0.5 mg/m³ |
|
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
NA |
Skin notation |
NA |
| Notes: | Notes: |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
1100 mg Ba/m³ |
|||||
| Carcinogenic classifications: EPA-CBD; NL; D, TLV-A4 | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Barium NIOSH: Pocket Guide to Chemical Hazards - Barium chloride (as Ba) Literature References
|
Last Updated Date : 04/02/2024
ARSENIC, ORGANIC COMPOUNDS †
| CAS # | 7440-38-2 |
|---|---|
| Formula |
As |
| Synonyms |
Synonyms vary depending upon the specific organic arsenic compound. |
| Physical description | Varies with specific organic arsenic compound. | ||
|---|---|---|---|
| Boiling point | Molecular weight | ||
| Freezing point/melting point | Vapor pressure | depends upon the specific compound | |
| Flash point | Vapor density | ||
| Specific gravity | Ionization potential | ||
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | A202 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | |
| Sampling time* | |
| Sampling volume (TWA)* | |
| Sampling flow rate (TWA)* | |
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | |
| Method reference | |
| Notes | Call the SLTC before sampling. Specialized equipment required for analysis of these samples cited in NIOSH Method 5022 is presently not available at the SLTC. |
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.5 mg/m³ |
REL-TWA | TLV-TWA | PEL-TWA |
0.2 mg/m³ |
||
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
NA |
Skin notation |
N |
| Notes: |
Notes:
Not established |
Notes:
Not established |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: Not listed | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Organoarsenic compound, N.O.S. NIOSH: Pocket Guide to Chemical Hazards - Arsenic (organic compounds, as As) Literature References
|
Last Updated Date : 01/29/2021
ARSENIC, INORGANIC COMPOUNDS (as As)‡
| CAS # | 7440-38-2 |
|---|---|
| Formula |
As |
| Synonyms |
arsenic metal; arsenia; others vary depending upon the specific arsenic compound. |
| Physical description | Silver-gray or tin-white metal, brittle odorless solid. | ||
|---|---|---|---|
| Boiling point | 1135°F (sublimes) | Molecular weight | 74.92 |
| Freezing point/melting point | 1135°F (sublimes) | Vapor pressure | 0 mmHg (approx) |
| Flash point | Vapor density | ||
| Specific gravity | 5.73 (metal) | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | 3 | NFPA fire rating | 2 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 0260 (high sensitivity) | |
|---|---|---|
| Sampling group | METALSSG-1 | |
| Sampler/Sampling media | Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001] | |
| Sampling time* | 240-480 min |
|
| Sampling volume (TWA)* | 480-960 L |
|
| Sampling flow rate (TWA)* | 2 L/min |
|
| Sampling volume (STEL/Peak/C)* | ||
| Sampling flow rate (STEL/Peak/C)* | ||
| Analytical method instruments | ICP | |
| Method reference | OSHA 5003 (fully validated) | |
| Notes | The METALSSG-1 sampling group members are analyzed using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) to target the expanded standards metals As, Cd, and Pb with high sensitivity (clean samples and smear tabs only). If arsenic is the only analyte of interest, use the single analyte code 0260. If the filter is not overloaded, samples may be collected up to an 8-hour period. If As, Cd, Cu, Fe, Pb or Zn are detected, results will be provided. |
|
| Special requirements | For volatile arsenic compounds, a sodium carbonate-impregnated BUP is required in conjunction with the MCE filter [225-9001]. |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with Whatman smear tab. [WHA1450993] |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
10 µg/m³ [5 µg/m³ Action Level] |
REL-TWA | TLV-TWA | PEL-TWA |
0.01 mg/m³ [0.005 mg/m³ Action Level] |
||
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C |
0.002 mg/m³ [15 minutes] |
TLV-C | PEL-C | |||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: |
Notes:
CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens. |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
5 mg/m³ |
|||||
| Carcinogenic classifications: EPA-A, IARC-1, NIOSH-Ca, NTP-K, OSHA-Ca, TLV-A1 |
Notes:
Ca |
||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Arsenic NIOSH: Pocket Guide to Chemical Hazards - Arsenic (Inorganic compounds, as As) Literature References
|
Last Updated Date : 04/03/2024
ANTIMONY & COMPOUNDS (as Sb)†
| CAS # | 7440-36-0 |
|---|---|
| Formula |
Sb |
| Synonyms |
antimony metal; antimony powder; stibium |
| Physical description | Silver-white, lustrous, hard, brittle solid with scale-like crystals, or a dark-gray, lustrous powder. | ||
|---|---|---|---|
| Boiling point | 2975°F | Molecular weight | 121.8 |
| Freezing point/melting point | 1166°F | Vapor pressure | 0 mmHg (approx) |
| Flash point | Vapor density | ||
| Specific gravity | 6.69 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 0230 | 0230 |
|---|---|---|
| Sampling group | METALSSG-2 | METALSSG-3 |
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0] | Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001] |
| Sampling time* | 240-480 min |
240-480 min |
| Sampling volume (TWA)* | 480-960 L |
480-960 L |
| Sampling flow rate (TWA)* | 2 L/min |
2 L/min |
| Sampling volume (STEL/Peak/C)* | ||
| Sampling flow rate (STEL/Peak/C)* | ||
| Analytical method instruments | ICP | ICP-MS |
| Method reference | OSHA ID-125G (fully validated) | OSHA ID-206 (fully validated) |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. Smaller filters recommended for sampling inside welding hoods. |
If the filter is not overloaded, samples may be collected up to an 8-hour period. Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as a specific form or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. The physical form of a sample (dust, mist, or fume) is identified by the compliance officer using available documentation of materials and processes. |
| Special requirements | For the entire suite of analytes listed in METALSSG-2, request analyte code 2587. |
For the entire suite of analytes listed in METALSSG-3, which may be found during soldering and brazing operations, request analyte code S131. |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | See sampling group information for media. |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.5 mg/m³ |
REL-TWA |
0.5 mg/m³ |
TLV-TWA | PEL-TWA |
0.5 mg/m³ |
|
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: | Notes: |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
50 mg/m³ |
|||||
| Carcinogenic classifications: IARC-2B (antimony trioxide) | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Antimony powder NIOSH: Pocket Guide to Chemical Hazards - Antimony Literature References
|
Last Updated Date : 04/03/2024
TUNGSTEN, SOLUBLE COMPOUNDS†
| CAS # | 7440-33-7 |
|---|---|
| Formula |
W |
| Synonyms |
Synonyms vary depending upon the specific soluble tungsten compound. |
| Physical description | Physical properties vary depending upon the specific soluble tungsten compound. | ||
|---|---|---|---|
| Boiling point | Molecular weight | ||
| Freezing point/melting point | Vapor pressure | depends upon the specific compound | |
| Flash point | Vapor density | ||
| Specific gravity | Ionization potential | ||
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2537 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0] |
| Sampling time* | 240 min |
| Sampling volume (TWA)* | 480 L |
| Sampling flow rate (TWA)* | 2 L/min |
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | ICP |
| Method reference | OSHA ID-213 (fully validated) |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. Analysis for this analyte is based on water solubility. |
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with Whatman smear tab. [WHA1450993] |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
1 mg/m³ (Construction and Maritime only) |
REL-TWA |
1 mg/m³ |
TLV-TWA |
3 mg/m³ (respirable particulate matter) [2016] |
PEL-TWA |
1 mg/m³ |
| PEL-STEL | REL-STEL |
3 mg/m³ |
TLV-STEL | PEL-STEL | |||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
|
Notes:
The OSHA PEL applies to Construction and Maritime Industries only. See 29 CFR 1926.55 Table 1 and 29 CFR 1915.1000 Table Z-Shipyards. |
Notes: | Notes: |
Notes:
Soluble compounds, as W |
||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Tungsten (soluble compounds, as W) NIOSH: Pocket Guide to Chemical Hazards - Tungsten (soluble compounds, as W) Literature References
|
Last Updated Date : 06/02/2022
TUNGSTEN, METAL & INSOLUBLE COMPOUNDS (as W)†
| CAS # | 7440-33-7 |
|---|---|
| Formula |
W |
| Synonyms |
tungsten metal; wolfram. Synonyms vary depending upon the specific insoluble tungsten compound. |
| Physical description | Hard, brittle, steel-gray to tin-white solid. | ||
|---|---|---|---|
| Boiling point | 10,701°F | Molecular weight | 183.9 |
| Freezing point/melting point | 6170°F | Vapor pressure | 0 mmHg (approx) |
| Flash point | Vapor density | ||
| Specific gravity | 19.3 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2536 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0] |
| Sampling time* | 240 min |
| Sampling volume (TWA)* | 480 L |
| Sampling flow rate (TWA)* | 2 L/min |
| Sampling volume (STEL/Peak/C)* | 30 L |
| Sampling flow rate (STEL/Peak/C)* | 2 L/min |
| Analytical method instruments | ICP |
| Method reference | OSHA ID-213 (fully validated) |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. |
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with Whatman smear tab. [WHA1450993] |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
5 mg/m³ (Construction and Maritime only) |
REL-TWA |
5 mg/m³ |
TLV-TWA |
3 mg/m³ (respirable particulate matter): Tungsten [7440-33-7] and compounds, in the absence of Cobalt, as W [2016]. 0.005 mg/m³ (thoracic particulate matter): Hard metals containing Cobalt [7440-48-4] and Tungsten carbide [12070-12-1], as Co [2015]. |
PEL-TWA |
5 mg/m³ |
| PEL-STEL | REL-STEL |
10 mg/m³ |
TLV-STEL | PEL-STEL |
10 mg/m³ |
||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
|
Notes:
The OSHA PEL applies to Construction and Maritime Industries only. See 29 CFR 1926.55 Table 1 and 29 CFR 1915.1000 Table Z-Shipyards. |
Notes:
The REL also applies to other insoluble tungsten compounds (as W). |
Notes:
respiratory sensitization (RSEN) |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Tungsten NIOSH: Pocket Guide to Chemical Hazards - Tungsten Literature References
|
Last Updated Date : 06/08/2022
TIN, ORGANIC COMPOUNDS (as Sn)†
| CAS # | Varies |
|---|---|
| Formula |
Varies with compounds |
| Synonyms |
organotin compounds: tributyltin fluoride [1983-10-4]; dibutyltin dilaurate [77-58-7]; tributyltin benzoate [4342-36-3]; methyltin mercaptide [57583-35-4]; stannous-2-ethyl hexanoate [301-10-0]; butyltin trichloride [1118-46-3]; bis-tributyltin oxide [56-35-9]; dibutyltin maleate [78-04-6]; triphenytin hydroxide [76-87-9]; tetramethyl tin [594-27-4]; Other synonyms vary depending upon the specific organotin compound. |
| Physical description | Appearance and odor vary depending upon the specific organotin compound. | ||
|---|---|---|---|
| Boiling point | Molecular weight | ||
| Freezing point/melting point | Vapor pressure | ||
| Flash point | Vapor density | ||
| Specific gravity | Ionization potential | ||
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2431 | 2431 | 2431 |
|---|---|---|---|
| Sampling group | |||
| Sampler/Sampling media | Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001] | ||
| Sampling time* | 100-200 min |
||
| Sampling volume (TWA)* | 200 L |
||
| Sampling flow rate (TWA)* | 1-2 L/min |
||
| Sampling volume (STEL/Peak/C)* | |||
| Sampling flow rate (STEL/Peak/C)* | |||
| Analytical method instruments | ICP-MS | ICP-MS | ICP-MS |
| Method reference | OSHA ID-224SG (partially validated) | OSHA ID-222SG (partially validated) | |
| Notes | Call the SLTC. OSHA ID-224SG is specific to dibutyltin maleate. OSHA ID-225SG is specific to triphenyltin hydroxide. |
Call the SLTC. OSHA ID-217SG is specific to butyltin trichloride. OSHA ID-218SG is specific to dibutyltin dilaurate. OSHA ID-219SG is specific to methyl tin mercaptide. |
Call the SLTC. OSHA ID-222SG is specific to tributyltin benzoate. OSHA ID-223SG is specific to tributyltin fluoride. OSHA ID-221SG is specific to stannous-2-ethyl hexanoate. |
| Special requirements | OSHA staff please call the SLTC prior to sampling. |
OSHA staff please call the SLTC prior to sampling. |
OSHA staff please call the SLTC prior to sampling. |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.1 mg/m³ |
REL-TWA |
0.1 mg/m³ |
TLV-TWA |
0.1 mg/m³ [1992] |
PEL-TWA |
0.1 mg/m³ |
| PEL-STEL | REL-STEL | TLV-STEL |
0.2 mg/m³ [1992] |
PEL-STEL |
0.2 mg/m³ |
||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
| Notes: |
Notes:
The REL applies to all organic tin compounds except cyhexatin. |
Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
25 mg/m³ (as Sn) |
|||||
| Carcinogenic classifications: TLV-A4 | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Tin NIOSH: Pocket Guide to Chemical Hazards - Tin (organic compounds, as Sn) Literature References
|
Last Updated Date : 01/13/2021
TIN, INORGANIC COMPOUNDS (EXCEPT OXIDES) (as Sn)†
| CAS # | 7440-31-5 |
|---|---|
| Formula |
Sn |
| Synonyms |
metallic tin; tin flake; tin metal; tin powder |
| Physical description | Gray to almost silver-white, ductile, malleable, lustrous solid. | ||
|---|---|---|---|
| Boiling point | 4545°F | Molecular weight | 118.7 |
| Freezing point/melting point | 449°F | Vapor pressure | depends upon the specific compound |
| Flash point | Vapor density | ||
| Specific gravity | 7.28 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2430 |
|---|---|
| Sampling group | METALSSG-3 |
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) [MAWP037A0] |
| Sampling time* | 240-480 min |
| Sampling volume (TWA)* | 480-960 L |
| Sampling flow rate (TWA)* | 2 L/min |
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | ICP-MS |
| Method reference | OSHA ID-206 (fully validated) |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. |
| Special requirements | For the entire suite of analytes listed in METALSSG-3, which may be found during soldering and brazing operations, request analyte code S131. |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | See sampling group information for media. |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
2 mg/m³ |
REL-TWA |
2 mg/m³ |
TLV-TWA | PEL-TWA |
2 mg/m³ |
|
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: | Notes: |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
100 mg/m³ |
|||||
| Carcinogenic classifications: Not listed | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Tin NIOSH: Pocket Guide to Chemical Hazards - Tin Literature References
|
Last Updated Date : 07/15/2025
THALLIUM, SOLUBLE COMPOUNDS†
| CAS # | 7440-28-0 |
|---|---|
| Formula |
Tl |
| Synonyms |
Synonyms vary depending upon the specific soluble thallium compound. |
| Physical description | Light-gray to tan powder with a slightly aromatic odor. | ||
|---|---|---|---|
| Boiling point | Molecular weight | 358.6 | |
| Freezing point/melting point | 302°F | Vapor pressure | depends upon the specific compound |
| Flash point | 420°F | Vapor density | |
| Specific gravity | 1.10 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2420 | |
|---|---|---|
| Sampling group | ||
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0] | |
| Sampling time* | 240-480 min |
|
| Sampling volume (TWA)* | 960 L |
|
| Sampling flow rate (TWA)* | 2 L/min |
|
| Sampling volume (STEL/Peak/C)* | ||
| Sampling flow rate (STEL/Peak/C)* | ||
| Analytical method instruments | AAS/AES | |
| Method reference | OSHA ID-121 (fully validated) | |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. Analysis for this analyte is based on water solubility. |
|
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with Whatman smear tab. [WHA1450993] |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.1 mg/m³ |
REL-TWA |
0.1 mg/m³ |
TLV-TWA |
0.02 mg/m³ (inhalable particulate matter) [2009] |
PEL-TWA |
0.1 mg/m³ |
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
| Notes: | Notes: | Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
15 mg/m³ |
|||||
| Carcinogenic classifications: | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Thallium NIOSH: Pocket Guide to Chemical Hazards - Thallium (soluble compounds, as Tl) Literature References
|
Last Updated Date : 01/29/2021