BERYLLIUM & COMPOUNDS (as Be)‡

Chemical Identification

CAS # 7440-41-7
Formula

Be

Synonyms

Synonyms vary depending upon the specific beryllium compound.

Physical Properties

Physical description hard, brittle, gray-white solid, metal
Boiling point 4532°F Molecular weight 9.0
Freezing point/melting point 2349°F Vapor pressure 0 mmHg (approx)
Flash point Vapor density
Specific gravity 1.85 (metal) Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL) 2349°F
NFPA health rating 3 NFPA fire rating 1
NFPA reactivity rating 0 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 0365 (high sensitivity)
Sampling group
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) [MAWP037A0]
Sampling time*

240 min

Sampling volume (TWA)*

480 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*

30 L

Sampling flow rate (STEL/Peak/C)*

2 L/min

Analytical method instruments ICP-AES
Method reference OSHA 1023 (fully validated)
Notes

Results are provided for the presence and amount or concentration of a specific element or elements.

The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes.

Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Wipe with Whatman smear tab. [WHA1450993]

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.2 µg/m³ [0.1 µg/m³ Action Level]

REL-TWA TLV-TWA PEL-TWA

0.0002 mg/m³

PEL-STEL

2 µg/m³

REL-STEL TLV-STEL PEL-STEL

0.002 mg/m³

PEL-C REL-C TLV-C PEL-C

0.025 mg/m³

Skin notation

N

Skin notation

N

Skin notation

Y

Skin notation

N

Notes:

See 29 CFR 1910.1024, Beryllium. See 29 CFR 1910.1000 Table Z-2for any operations or sectors where the exposure limits in 1910.1024 are stayed or otherwise not in effect.

Notes:

CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens

Notes:

Visit the ACGIH TLV site for specific data
skin, dermal sensitizer (DSEN) (soluble compounds), respiratory sensitizer (RSEN) (soluble and insoluble compounds)

Notes:

See also California Code of Regulations, Title 8 §1535.1 Beryllium., §5205. Beryllium., and §8359.1 Beryllium.

Health factors:  See NIH-NLM PubChem. IDLH

4 mg/m³

Carcinogenic classifications: IARC-1, NIOSH-Ca, NTP-K, TLV-A1, EPA-B1; L; CBD Notes:

Ca

AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

--/0.025 mg/m³/0.1 mg/m³

Additional Resources and Literature References

Last Updated Date : 03/27/2024

BARIUM, SOLUBLE COMPOUNDS (EXCEPT BARIUM SULFATE)†

Chemical Identification

CAS # 7440-39-3
Formula

Ba

Synonyms

Synonyms vary depending upon the specific soluble barium compound.

Physical Properties

Physical description A silver to white metallic, odorless solid
Boiling point 2984°F Molecular weight 137.33
Freezing point/melting point 1337°F Vapor pressure 10 mmHg at 1920°F
Flash point Vapor density
Specific gravity 3.51 at 68°F Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 0310
Sampling group
Sampler/Sampling media Tared low-ash 37 mm PVC filter, 5 microns [SLTC108]
Sampling time*

240-480 min

Sampling volume (TWA)*

480-960 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments Gravimetric
Method reference OSHA PV2121 (partially validated)
Notes

Samples are first analyzed gravimetrically. If the gravimetric result of a sample yields a concentration below the permissible exposure limit (PEL), the SLTC will report the calculated air concentration from the gravimetric result, qualified as less than or equal to the gravimetric result; no further work on the sample will be performed.

If the gravimetric result indicates an air concentration greater than the PEL, the sample will proceed for elemental analysis. Results will be reported from the elemental analysis for the element only; the stated identity of the actual sample contents is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes.

Analysis for this analyte is based on water solubility.

Special requirements

FOR TOTAL DUST SAMPLES, DO NOT USE A CYCLONE!!

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Wipe with Whatman smear tab. [WHA1450993]

Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.5 mg/m³

REL-TWA

0.5 mg/m³

TLV-TWA PEL-TWA

0.5 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

NA

Skin notation

NA

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes:

Visit the ACGIH TLV site for specific data

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

1100 mg Ba/m³ 

Carcinogenic classifications: EPA-CBD; NL; D, TLV-A4 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 04/02/2024

ARSENIC, ORGANIC COMPOUNDS †

Chemical Identification

CAS # 7440-38-2
Formula

As

Synonyms

Synonyms vary depending upon the specific organic arsenic compound.

Physical Properties

Physical description Varies with specific organic arsenic compound.
Boiling point Molecular weight
Freezing point/melting point Vapor pressure depends upon the specific compound
Flash point Vapor density
Specific gravity Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) A202
Sampling group
Sampler/Sampling media
Sampling time*
Sampling volume (TWA)*
Sampling flow rate (TWA)*
Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments
Method reference
Notes

Call the SLTC before sampling. Specialized equipment required for analysis of these samples cited in NIOSH Method 5022 is presently not available at the SLTC.

Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.5 mg/m³

REL-TWA TLV-TWA PEL-TWA

0.2 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

NA

Skin notation

N

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes:

Not established

Notes:

Not established

Notes:
Health factors:  See NIH-NLM PubChem. IDLH
Carcinogenic classifications: Not listed Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/29/2021

ARSENIC, INORGANIC COMPOUNDS (as As)‡

Chemical Identification

CAS # 7440-38-2
Formula

As

Synonyms

arsenic metal; arsenia; others vary depending upon the specific arsenic compound.

Physical Properties

Physical description Silver-gray or tin-white metal, brittle odorless solid.
Boiling point 1135°F (sublimes) Molecular weight 74.92
Freezing point/melting point 1135°F (sublimes) Vapor pressure 0 mmHg (approx)
Flash point Vapor density
Specific gravity 5.73 (metal) Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating 3 NFPA fire rating 2
NFPA reactivity rating 0 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 0260 (high sensitivity)
Sampling group METALSSG-1
Sampler/Sampling media Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001]
Sampling time*

240-480 min
 

Sampling volume (TWA)*

480-960 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments ICP
Method reference OSHA 5003 (fully validated)
Notes

The METALSSG-1 sampling group members are analyzed using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) to target the expanded standards metals As, Cd, and Pb with high sensitivity (clean samples and smear tabs only).

If arsenic is the only analyte of interest, use the single analyte code 0260. If the filter is not overloaded, samples may be collected up to an 8-hour period. If As, Cd, Cu, Fe, Pb or Zn are detected, results will be provided.

Special requirements

For volatile arsenic compounds, a sodium carbonate-impregnated BUP is required in conjunction with the MCE filter [225-9001].

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Wipe with Whatman smear tab. [WHA1450993]

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

10 µg/m³ [5 µg/m³ Action Level]

REL-TWA TLV-TWA PEL-TWA

0.01 mg/m³ [0.005 mg/m³ Action Level]

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C

0.002 mg/m³ [15 minutes]

TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

See See 29 CFR 1910.1018, Arsenic.

Notes:

CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens.

Notes:

Visit the ACGIH TLV site for specific data
BEI®. TLV for lead arsenate (3687-31-8) was withdrawn for insufficient data in 2009.

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

5 mg/m³

Carcinogenic classifications: EPA-A, IARC-1, NIOSH-Ca, NTP-K, OSHA-Ca, TLV-A1 Notes:

Ca

AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 04/03/2024

ANTIMONY & COMPOUNDS (as Sb)†

Chemical Identification

CAS # 7440-36-0
Formula

Sb

Synonyms

antimony metal; antimony powder; stibium

Physical Properties

Physical description Silver-white, lustrous, hard, brittle solid with scale-like crystals, or a dark-gray, lustrous powder.
Boiling point 2975°F Molecular weight 121.8
Freezing point/melting point 1166°F Vapor pressure 0 mmHg (approx)
Flash point Vapor density
Specific gravity 6.69 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 0230 0230
Sampling group METALSSG-2 METALSSG-3
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0] Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001]
Sampling time*

240-480 min

240-480 min

Sampling volume (TWA)*

480-960 L

480-960 L

Sampling flow rate (TWA)*

2 L/min

2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments ICP ICP-MS
Method reference OSHA ID-125G (fully validated) OSHA ID-206 (fully validated)
Notes

Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. Smaller filters recommended for sampling inside welding hoods.

If the filter is not overloaded, samples may be collected up to an 8-hour period. Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as a specific form or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. The physical form of a sample (dust, mist, or fume) is identified by the compliance officer using available documentation of materials and processes.

Special requirements

For the entire suite of analytes listed in METALSSG-2, request analyte code 2587.

For the entire suite of analytes listed in METALSSG-3, which may be found during soldering and brazing operations, request analyte code S131.

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

See sampling group information for media.

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.5 mg/m³

REL-TWA

0.5 mg/m³

TLV-TWA PEL-TWA

0.5 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes:

Visit the ACGIH TLV site for specific data

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

50 mg/m³

Carcinogenic classifications: IARC-2B (antimony trioxide) Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 04/03/2024

TUNGSTEN, SOLUBLE COMPOUNDS†

Chemical Identification

CAS # 7440-33-7
Formula

W

Synonyms

Synonyms vary depending upon the specific soluble tungsten compound.

Physical Properties

Physical description Physical properties vary depending upon the specific soluble tungsten compound.
Boiling point Molecular weight
Freezing point/melting point Vapor pressure depends upon the specific compound
Flash point Vapor density
Specific gravity Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2537
Sampling group
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0]
Sampling time*

240 min

Sampling volume (TWA)*

480 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments ICP
Method reference OSHA ID-213 (fully validated)
Notes

Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes.

Analysis for this analyte is based on water solubility.

Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Wipe with Whatman smear tab. [WHA1450993]

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

1 mg/m³ (Construction and Maritime only)

REL-TWA

1 mg/m³

TLV-TWA

3 mg/m³ (respirable particulate matter) [2016]

PEL-TWA

1 mg/m³

PEL-STEL REL-STEL

3 mg/m³

TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

The OSHA PEL applies to Construction and Maritime Industries only. See 29 CFR 1926.55 Table 1 and 29 CFR 1915.1000 Table Z-Shipyards.

Notes: Notes: Notes:

Soluble compounds, as W

Health factors:  See NIH-NLM PubChem. IDLH
Carcinogenic classifications: Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 06/02/2022

TUNGSTEN, METAL & INSOLUBLE COMPOUNDS (as W)†

Chemical Identification

CAS # 7440-33-7
Formula

W

Synonyms

tungsten metal; wolfram. Synonyms vary depending upon the specific insoluble tungsten compound.

Physical Properties

Physical description Hard, brittle, steel-gray to tin-white solid.
Boiling point 10,701°F Molecular weight 183.9
Freezing point/melting point 6170°F Vapor pressure 0 mmHg (approx)
Flash point Vapor density
Specific gravity 19.3 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2536
Sampling group
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0]
Sampling time*

240 min

Sampling volume (TWA)*

480 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*

30 L

Sampling flow rate (STEL/Peak/C)*

2 L/min

Analytical method instruments ICP
Method reference OSHA ID-213 (fully validated)
Notes

Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes.

Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Wipe with Whatman smear tab. [WHA1450993]

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

5 mg/m³ (Construction and Maritime only)

REL-TWA

5 mg/m³

TLV-TWA

3 mg/m³ (respirable particulate matter): Tungsten [7440-33-7] and compounds, in the absence of Cobalt, as W [2016]. 0.005 mg/m³ (thoracic particulate matter): Hard metals containing Cobalt [7440-48-4] and Tungsten carbide [12070-12-1], as Co [2015].

PEL-TWA

5 mg/m³

PEL-STEL REL-STEL

10 mg/m³

TLV-STEL PEL-STEL

10 mg/m³

PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

The OSHA PEL applies to Construction and Maritime Industries only. See 29 CFR 1926.55 Table 1 and 29 CFR 1915.1000 Table Z-Shipyards.

Notes:

The REL also applies to other insoluble tungsten compounds (as W).

Notes:

respiratory sensitization (RSEN)

Notes:
Health factors:  See NIH-NLM PubChem. IDLH
Carcinogenic classifications: Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 06/08/2022

TIN, ORGANIC COMPOUNDS (as Sn)†

Chemical Identification

CAS # Varies
Formula

Varies with compounds

Synonyms

organotin compounds: tributyltin fluoride [1983-10-4]; dibutyltin dilaurate [77-58-7]; tributyltin benzoate [4342-36-3]; methyltin mercaptide [57583-35-4]; stannous-2-ethyl hexanoate [301-10-0]; butyltin trichloride [1118-46-3]; bis-tributyltin oxide [56-35-9]; dibutyltin maleate [78-04-6]; triphenytin hydroxide [76-87-9]; tetramethyl tin [594-27-4]; Other synonyms vary depending upon the specific organotin compound.

Physical Properties

Physical description Appearance and odor vary depending upon the specific organotin compound.
Boiling point Molecular weight
Freezing point/melting point Vapor pressure
Flash point Vapor density
Specific gravity Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2431 2431 2431
Sampling group
Sampler/Sampling media Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001]
Sampling time*

100-200 min

Sampling volume (TWA)*

200 L

Sampling flow rate (TWA)*

1-2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments ICP-MS ICP-MS ICP-MS
Method reference OSHA ID-224SG (partially validated) OSHA ID-222SG (partially validated)
Notes

Call the SLTC. OSHA ID-224SG is specific to dibutyltin maleate. OSHA ID-225SG is specific to triphenyltin hydroxide.

Call the SLTC. OSHA ID-217SG is specific to butyltin trichloride. OSHA ID-218SG is specific to dibutyltin dilaurate. OSHA ID-219SG is specific to methyl tin mercaptide.

Call the SLTC. OSHA ID-222SG is specific to tributyltin benzoate. OSHA ID-223SG is specific to tributyltin fluoride. OSHA ID-221SG is specific to stannous-2-ethyl hexanoate.

Special requirements

OSHA staff please call the SLTC prior to sampling.

OSHA staff please call the SLTC prior to sampling.

OSHA staff please call the SLTC prior to sampling.

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.1 mg/m³

REL-TWA

0.1 mg/m³

TLV-TWA

0.1 mg/m³ [1992]

PEL-TWA

0.1 mg/m³

PEL-STEL REL-STEL TLV-STEL

0.2 mg/m³ [1992]

PEL-STEL

0.2 mg/m³

PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

Y

Skin notation

Y

Skin notation

Y

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes:

The REL applies to all organic tin compounds except cyhexatin.

Notes: Notes:
Health factors:  See NIH-NLM PubChem. IDLH

25 mg/m³ (as Sn)

Carcinogenic classifications: TLV-A4 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/13/2021

TIN, INORGANIC COMPOUNDS (EXCEPT OXIDES) (as Sn)†

Chemical Identification

CAS # 7440-31-5
Formula

Sn

Synonyms

metallic tin; tin flake; tin metal; tin powder

Physical Properties

Physical description Gray to almost silver-white, ductile, malleable, lustrous solid.
Boiling point 4545°F Molecular weight 118.7
Freezing point/melting point 449°F Vapor pressure depends upon the specific compound
Flash point Vapor density
Specific gravity 7.28 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2430
Sampling group METALSSG-3
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) [MAWP037A0]
Sampling time*

240-480 min

Sampling volume (TWA)*

480-960 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments ICP-MS
Method reference OSHA ID-206 (fully validated)
Notes

Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes.

Special requirements

For the entire suite of analytes listed in METALSSG-3, which may be found during soldering and brazing operations, request analyte code S131.

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

See sampling group information for media.

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

2 mg/m³

REL-TWA

2 mg/m³

TLV-TWA PEL-TWA

2 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes:

Visit the ACGIH TLV site for specific data

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

100 mg/m³

Carcinogenic classifications: Not listed Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 07/15/2025

THALLIUM, SOLUBLE COMPOUNDS†

Chemical Identification

CAS # 7440-28-0
Formula

Tl

Synonyms

Synonyms vary depending upon the specific soluble thallium compound.

Physical Properties

Physical description Light-gray to tan powder with a slightly aromatic odor.
Boiling point Molecular weight 358.6
Freezing point/melting point 302°F Vapor pressure depends upon the specific compound
Flash point 420°F Vapor density
Specific gravity 1.10 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2420
Sampling group
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0]
Sampling time*

240-480 min

Sampling volume (TWA)*

960 L

Sampling flow rate (TWA)*

2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments AAS/AES
Method reference OSHA ID-121 (fully validated)
Notes

Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes.

Analysis for this analyte is based on water solubility.

Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Wipe with Whatman smear tab. [WHA1450993]

Bulk Method

Available

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.1 mg/m³

REL-TWA

0.1 mg/m³

TLV-TWA

0.02 mg/m³ (inhalable particulate matter) [2009]

PEL-TWA

0.1 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

Y

Skin notation

Y

Skin notation

Y

Skin notation

Y

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes: Notes:
Health factors:  See NIH-NLM PubChem. IDLH

15 mg/m³

Carcinogenic classifications: Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/29/2021