IRON SALTS, SOLUBLE (as Fe)†
| CAS # | 7439-89-6 |
|---|---|
| Formula |
varies with compounds |
| Synonyms |
FeSO₄: ferrous sulfate; iron(II) sulfate FeCl₂: ferrous chloride; iron(II) chloride Fe(NO₃)₃: ferric nitrate; iron(III) nitrate Fe(SO₄)₃: ferric sulfate; iron(III) sulfate FeCl₃: ferric chloride; iron(III) chloride |
| Physical description | Appearance and odor vary depending upon the specific soluble iron salt. | ||
|---|---|---|---|
| Boiling point | 288°F | Molecular weight | 130.2 |
| Freezing point/melting point | Vapor pressure | depends upon the specific compound | |
| Flash point | Vapor density | ||
| Specific gravity | Ionization potential | ||
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1522 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | Mixed cellulose ester filter (MCEF) 0.8 micron (37 mm) and filter spacer with Na₂CO₃ impregnated backup pad, in a 3-piece cassette [SKC 225-9001] |
| Sampling time* | 240-480 min |
| Sampling volume (TWA)* | 480-960 L |
| Sampling flow rate (TWA)* | 2 L/min |
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | ICP |
| Method reference | OSHA ID-125G (fully validated) |
| Notes | Results are provided for the presence and amount or concentration of a specific element or elements. The stated identity of the actual sample contents (such as specific form, valence state, or compound) is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. Analysis for this analyte is based on water solubility. |
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
1 mg/m³ (Construction and Maritime Industries ONLY) |
REL-TWA |
1 mg/m³ |
TLV-TWA |
1 mg/m³ [1990] |
PEL-TWA |
1 mg/m³ |
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
|
Notes:
The OSHA PEL applies to Construction and Maritime Industries only. See 29 CFR 1926.55 Table 1 and 29 CFR 1915.1000 Table Z-Shipyards. |
Notes: | Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: Not listed | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - See individual compounds NIOSH: Pocket Guide to Chemical Hazards - Iron salts (soluble, as Fe) Literature References
|
Last Updated Date : 06/02/2022
ALUMINUM, METAL (as Al)†
| CAS # | 7429-90-5 |
|---|---|
| Formula |
Al |
| Synonyms |
aluminum; aluminum metal; aluminum powder; elemental aluminum |
| Physical description | Silvery-white, malleable, ductile, odorless metal. | ||
|---|---|---|---|
| Boiling point | 4221°F | Molecular weight | 27.0 |
| Freezing point/melting point | 1220°F | Vapor pressure | 0 mmHg (approx) |
| Flash point | Vapor density | ||
| Specific gravity | 2.70 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | 0 | NFPA fire rating | 3 |
| NFPA reactivity rating | 1 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | A100 (total); request using analyte code 9135 | A110 (resp); request using analyte code 9130 |
|---|---|---|
| Sampling group | ||
| Sampler/Sampling media | Tared low-ash 37 mm PVC filter, 5 microns [SLTC108] | Tared low-ash 37 mm PVC filter, 5 microns, preceded by 10 mm nylon Dorr-Oliver cyclone for respirable samples. [SLTC108] |
| Sampling time* | 240-480 min |
240-480 min |
| Sampling volume (TWA)* | 480-960 L |
816 L |
| Sampling flow rate (TWA)* | 2 L/min |
1.7 L/min ±5% |
| Sampling volume (STEL/Peak/C)* | ||
| Sampling flow rate (STEL/Peak/C)* | ||
| Analytical method instruments | Gravimetric | Gravimetric |
| Method reference | OSHA PV2121 (partially validated) | OSHA PV2121 (partially validated) |
| Notes | Samples are first analyzed gravimetrically. If the gravimetric result of a sample yields a concentration below the permissible exposure limit (PEL), the SLTC will report the calculated air concentration from the gravimetric result, qualified as less than or equal to the gravimetric result; no further work on the sample will be performed. If the gravimetric result indicates an air concentration greater than the PEL, the sample will proceed for elemental analysis. Results will be reported from the elemental analysis for the element only; the stated identity of the actual sample contents is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. |
Samples are first analyzed gravimetrically. If the gravimetric result of a sample yields a concentration below the permissible exposure limit (PEL), the SLTC will report the calculated air concentration from the gravimetric result, qualified as less than or equal to the gravimetric result; no further work on the sample will be performed. If the gravimetric result indicates an air concentration greater than the PEL, the sample will proceed for elemental analysis. Results will be reported from the elemental analysis for the element only; the stated identity of the actual sample contents is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. The standard applies to the Respirable Fraction. Samples must be collected with a Dorr-Oliver cyclone. |
| Special requirements | FOR TOTAL DUST SAMPLES, DO NOT USE A CYCLONE!! |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method | Available |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
15 mg/m³ (total dust), 5 mg/m³ (respirable fraction) |
REL-TWA |
10 mg/m³ (total dust), 5 mg/m³ (respirable fraction) |
TLV-TWA | PEL-TWA |
10 mg/m³ (total dust), 5 mg/m³ (respirable fraction) |
|
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: | Notes: |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: TLV-A4 | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Aluminum powder, coated NIOSH: Pocket Guide to Chemical Hazards - Aluminum Literature References
|
Last Updated Date : 03/27/2024
SULFOMETURON-METHYL
| CAS # | 74222-97-2 |
|---|---|
| Formula |
C₁₅H₁₆N₄O₅S |
| Synonyms |
methyl 2-[[[[[4,6-dimethyl-2-pyrimidinyl]amino]-carbonyl]amino]sulfonyl]benzoate |
| Physical description | White solid. | ||
|---|---|---|---|
| Boiling point | Molecular weight | 364.4 | |
| Freezing point/melting point | 397.4-401°F | Vapor pressure | |
| Flash point | Vapor density | ||
| Specific gravity | Ionization potential | ||
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | |||
|---|---|---|---|
| Sampling group | |||
| Sampler/Sampling media | |||
| Sampling time* | |||
| Sampling volume (TWA)* | |||
| Sampling flow rate (TWA)* | |||
| Sampling volume (STEL/Peak/C)* | |||
| Sampling flow rate (STEL/Peak/C)* | |||
| Analytical method instruments | |||
| Method reference | |||
| Notes | |||
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA | REL-TWA | TLV-TWA |
5 mg/m³ (inhalable fraction and vapor) [1991] |
PEL-TWA |
3.5 mg/m³ |
||
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
NA |
Skin notation |
NA |
Skin notation |
N |
Skin notation |
N |
|
Notes:
Not established |
Notes:
Not established |
Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: TLV-A4 | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Not listed NIOSH: Pocket Guide to Chemical Hazards - Not listed Literature References
|
Last Updated Date : 01/12/2021
METHOXYCHLOR†
| CAS # | 72-43-5 |
|---|---|
| Formula |
C₁₆H₁₅Cl₃O₂ |
| Synonyms |
p,p'-dimethoxydiphenylftrichloroethane; DMDT; methoxy-DDT; 2,2-bis(p-methoxyphenyl)-1,1,1-trichloroethane; 1,1,1-trichloro-2,2-bis-(p-methoxyphenyl)ethane |
| Physical description | Colorless to light-yellow crystals with a slight, fruity odor. | ||
|---|---|---|---|
| Boiling point | decomposes | Molecular weight | 345.7 |
| Freezing point/melting point | 171°F | Vapor pressure | Very low |
| Flash point | Vapor density | 12 | |
| Specific gravity | 1.41 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1646 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | OSHA versatile sampler (OVS-2) - 13 mm XAD-2 tube (270/140 mg) with GFF enclosed [SKC 226-30-16] |
| Sampling time* |
|
| Sampling volume (TWA)* |
60 L |
| Sampling flow rate (TWA)* |
1 L/min |
| Sampling volume (STEL/Peak/C)* |
|
| Sampling flow rate (STEL/Peak/C)* |
|
| Analytical method instruments | GC-ECD |
| Method reference | OSHA PV2038 (partially validated) |
| Notes |
|
| Special requirements |
|
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media |
|
|---|---|
| Bulk Method |
Limit the amount of bulk submitted to 1 g or 1 mL. |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
15 mg/m³ (total dust) |
REL-TWA |
|
TLV-TWA |
10 mg/m³ [1992] |
PEL-TWA |
10 mg/m³ |
| PEL-STEL |
|
REL-STEL |
|
TLV-STEL |
|
PEL-STEL |
|
| PEL-C |
|
REL-C |
|
TLV-C |
|
PEL-C |
|
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: |
Notes:
CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. (LOQ 0.07 mg/m³) See Appendix A, NIOSH Potential Occupational Carcinogens. |
Notes:
|
Notes:
|
||||
| Health factors: See NIH-NLM PubChem. | IDLH |
5000 mg/m³ |
|||||
| Carcinogenic classifications: IARC-3, NIOSH-Ca, TLV-A4, EPA-D |
Notes:
Ca |
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
|
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Methoxyclor NIOSH: Pocket Guide to Chemical Hazards - Methoxyclor Literature References
|
Last Updated Date : 01/05/2021
ENDRIN†
| CAS # | 72-20-8 |
|---|---|
| Formula |
C₁₂H₈Cl₆O |
| Synonyms |
1,2,3,4,10,10-hexachloro-6,7-epoxy-1,4,4a,5,6,7,8,8a-octahydro-1,4-endo,endo-5,8-dimethanonaphthalene; hexadrin |
| Physical description | Colorless to tan, crystalline solid with a mild, chemical odor. | ||
|---|---|---|---|
| Boiling point | 245°C (decomposes) | Molecular weight | 380.9 |
| Freezing point/melting point | 473°F (decomposes) | Vapor pressure | low |
| Flash point | 80°F (commercial product may contain flammable liquid) | Vapor density | |
| Specific gravity | 1.7 | Ionization potential | |
| Lower explosive limit (LEL) | 1.1% (commercial product) | Upper explosive limit (UEL) | 7% (commercial product) |
| NFPA health rating | 2 | NFPA fire rating | 0 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1017 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | 0.8 µm Cellulose ester membrane + Chromosorb 102, (100/50 mg) [SKC 225-5 & SKC 226-107] |
| Sampling time* |
|
| Sampling volume (TWA)* |
12-400 L |
| Sampling flow rate (TWA)* |
0.5-1 L/min |
| Sampling volume (STEL/Peak/C)* |
|
| Sampling flow rate (STEL/Peak/C)* |
|
| Analytical method instruments | GC-ECD |
| Method reference | NIOSH 5519 (fully validated) |
| Notes |
|
| Special requirements |
|
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media |
|
|---|---|
| Bulk Method |
|
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.1 mg/m³ |
REL-TWA |
0.1 mg/m³ |
TLV-TWA |
0.1 mg/m³ [1979] |
PEL-TWA |
0.1 mg/m³ |
| PEL-STEL |
|
REL-STEL |
|
TLV-STEL |
|
PEL-STEL |
|
| PEL-C |
|
REL-C |
|
TLV-C |
|
PEL-C |
|
| Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
| Notes: |
Notes:
|
Notes:
|
Notes:
|
||||
| Health factors: See NIH-NLM PubChem. | IDLH |
2 mg/m³ |
|||||
| Carcinogenic classifications: IARC-3, TLV-A4, EPA-D |
Notes:
|
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
|
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Endrin NIOSH: Pocket Guide to Chemical Hazards - Endrin Literature References
|
Last Updated Date : 01/29/2021
METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE)†
| CAS # | 71-55-6 |
|---|---|
| Formula |
C₂H₃Cl₃ |
| Synonyms |
chlorothene; 1,1,1-trichloroethane; 1,1,1-trichloroethane (stabilized) |
| Physical description | Colorless liquid with a sweet, chloroform-like odor. | ||
|---|---|---|---|
| Boiling point | 165°F | Molecular weight | 133.4 |
| Freezing point/melting point | -26.5°F | Vapor pressure | 100 mmHg |
| Flash point | >200°F | Vapor density | 4.6 |
| Specific gravity | 1.31 | Ionization potential | 11.00 eV |
| Lower explosive limit (LEL) | 7.5% | Upper explosive limit (UEL) | 12.5% |
| NFPA health rating | 2 | NFPA fire rating | 1 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1720 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | CSC tube (100/50 mg) [SKC 226-01] |
| Sampling time* |
|
| Sampling volume (TWA)* |
3 L |
| Sampling flow rate (TWA)* |
0.2 L/min |
| Sampling volume (STEL/Peak/C)* |
|
| Sampling flow rate (STEL/Peak/C)* |
|
| Analytical method instruments | GC-FID |
| Method reference | OSHA 14 (fully validated) |
| Notes |
|
| Special requirements |
|
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media |
|
|---|---|
| Bulk Method |
|
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
350 ppm (1900 mg/m³) |
REL-TWA |
|
TLV-TWA |
350 ppm [1992] |
PEL-TWA |
350 ppm (1900 mg/m³) |
| PEL-STEL |
|
REL-STEL |
|
TLV-STEL |
450 ppm [1992] |
PEL-STEL |
450 ppm (2450 mg/m³) |
| PEL-C |
|
REL-C |
350 ppm (1900 mg/m³) [15 minutes] |
TLV-C |
|
PEL-C |
800 ppm |
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: |
Notes:
|
Notes:
BEI® |
Notes:
|
||||
| Health factors: See NIH-NLM PubChem. | IDLH |
700 ppm |
|||||
| Carcinogenic classifications: IARC-3, TLV-A4, EPA-II |
Notes:
|
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
350 ppm/700 ppm/3500 ppm |
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - 1,1,1-Trichloroethane NIOSH: Pocket Guide to Chemical Hazards - Methyl chloroform Literature References
|
Last Updated Date : 01/05/2021
BENZENE‡
| CAS # | 71-43-2 |
|---|---|
| Formula |
C₆H₆ |
| Synonyms |
benzine; benzol; cyclohexatriene; phenyl hydride |
| Physical description | Highly flammable colorless to light-yellow liquid with a petroleum-like odor. | ||
|---|---|---|---|
| Boiling point | 176.2°F | Molecular weight | 78.11 |
| Freezing point/melting point | 41.9°F | Vapor pressure | 75 mmHg |
| Flash point | 12°F | Vapor density | 2.77 |
| Specific gravity | 0.88 | Ionization potential | 9.24 eV |
| Lower explosive limit (LEL) | 1.2% | Upper explosive limit (UEL) | 8% |
| NFPA health rating | 2 | NFPA fire rating | 3 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 0320 | 0320 |
|---|---|---|
| Sampling group | OVSG-1 | |
| Sampler/Sampling media | CSC tube (100/50 mg) [SKC 226-01] | SKC 575-002 Passive Sampler [SKC 575-002] |
| Sampling time* | 240 min (15 min STEL) |
240 min TWA; 10 min Peak; 15 min STEL (Note: SKC 575-002 Passive Samplers must be exposed for at least 10 min) |
| Sampling volume (TWA)* | 12 L |
|
| Sampling flow rate (TWA)* | 0.05 L/min |
|
| Sampling volume (STEL/Peak/C)* | 0.75 L |
|
| Sampling flow rate (STEL/Peak/C)* | 0.05 L/min |
|
| Analytical method instruments | GC-FID | GC-FID |
| Method reference | OSHA 5000 (fully validated) | OSHA 1005 v.2.1 (fully validated) |
| Notes | To obtain sampling and analytical error similar to that available with active sampling, knowledge of the atmospheric pressure and temperature are required, and these should be obtained using NIST-traceable devices. If that is not possible, temperature is assumed to be 22.2 °C, and the atmospheric pressure is estimated based on the elevation of the sampling location. When estimates are used in place of traceable measurements the sampling and analytical error associated with passive sampling is substantially increased, and this makes it more difficult to demonstrate over exposures after considering the 95% lower confidence limit. |
|
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method |
| Device | Detector tube | Detector tube | Detector tube | CMS Chip | CMS Chip |
|---|---|---|---|---|---|
| Model/Type | Gastec 121 | Matheson-Kitagawa 8014-118SC | Dräger - Benzene 5/b 6728071 | Benzene, 0.05-2.5 ppm range; Benzene, 0.2-10 ppm range | Benzene, 0.5-10 ppm range; Benzene, 10-250 ppm range |
|
Sampling information (see manufacturer instructions) |
1-4 strokes, 0.5-120 ppm range, uncertainty 16.4% for 50-20 ppm, 8.2% for 20-60 ppm | Follow mfr instructions, 0.2-100 ppm range | 20 strokes, 1-50 ppm range, 25% uncertainty |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
1 ppm |
REL-TWA |
0.1 ppm |
TLV-TWA | PEL-TWA |
1 ppm |
|
| PEL-STEL |
5 ppm |
REL-STEL |
1 ppm |
TLV-STEL | PEL-STEL |
5 ppm |
|
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
Y |
Skin notation |
Y |
|
Notes:
See 29 CFR 1910.1028, Benzene. See 29 CFR 1910.1000 Table Z-2 for any operations or sectors where the exposure limits in 1910.1028 are stayed or otherwise not in effect. |
Notes:
CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens. |
Notes:
Visit the ACGIH TLV site for specific data |
Notes:
Also See California Code of Regulations, Title 8, Sec 5218. |
||||
| Health factors: See NIH-NLM PubChem. | IDLH |
500 ppm |
|||||
| Carcinogenic classifications: EPA-A; K, IARC-1, NIOSH-Ca, NTP-K, OSHA-Ca, TLV-A1 |
Notes:
Ca |
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
50 ppm/150 ppm/1000 ppm |
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Benzene NIOSH: Pocket Guide to Chemical Hazards - Benzene Literature References
|
Last Updated Date : 04/02/2024
N-BUTYL ALCOHOL (N-BUTANOL)†
| CAS # | 71-36-3 |
|---|---|
| Formula |
C₄H₁₀O |
| Synonyms |
1-butanol, butyl alcohol, 1-hydroxybutane, n-propyl carbinol, butanol |
| Physical description | Colorless liquid with a strong, characteristic, mildly alcoholic odor. | ||
|---|---|---|---|
| Boiling point | 243°F | Molecular weight | 74.1 |
| Freezing point/melting point | -129°F | Vapor pressure | 15.51 mmHg |
| Flash point | 84°F | Vapor density | |
| Specific gravity | 0.81 | Ionization potential | 10.04 eV |
| Lower explosive limit (LEL) | 1.4% | Upper explosive limit (UEL) | 11.2% |
| NFPA health rating | 2 | NFPA fire rating | 3 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 0460 |
|---|---|
| Sampling group | OVSG-2 |
| Sampler/Sampling media | 2 Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of sorbent) connected in series [SKC 226-82], tube holder [SKC 222-3L-1], Type D cover [SKC 224-29D] |
| Sampling time* | 240 min |
| Sampling volume (TWA)* | 12 L |
| Sampling flow rate (TWA)* | 0.05 L/min |
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | GC-FID |
| Method reference | OSHA 5001 (fully validated) |
| Notes | Separate tubes and seal each after sampling. |
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method |
| Device | Detector tube | Detector tube | Detector tube |
|---|---|---|---|
| Model/Type | Dräger - Alcohol 25/a, 8101631 | Gastec 114 | Matheson-Kitagawa 8014-189U |
|
Sampling information (see manufacturer instructions) |
10 strokes, approx 50-5000 ppm range, uncertainty approx 41% | 3 strokes, 1-150 ppm range, uncertainty 25% for 2.5-30 ppm, 16% for 30-150 ppm | 2 or 4 strokes, approx 4-300 ppm range |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
100 ppm (300 mg/m³) |
REL-TWA | TLV-TWA | PEL-TWA | |||
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C |
50 ppm (150 mg/m³) |
TLV-C | PEL-C |
50 ppm (150 mg/m³) |
||
| Skin notation |
N |
Skin notation |
Y |
Skin notation |
N |
Skin notation |
Y |
| Notes: | Notes: |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
1400 ppm |
|||||
| Carcinogenic classifications: EPA-D |
Notes:
10% of LEL |
||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - N-Butyl alcohol NIOSH: Pocket Guide to Chemical Hazards - n-Butyl alcohol Literature References
|
Last Updated Date : 04/05/2024
N-PROPYL ALCOHOL (N-PROPANOL)†
| CAS # | 71-23-8 |
|---|---|
| Formula |
C₃H₈O |
| Synonyms |
propyl alcohol; 1-propanol; ethyl carbinol |
| Physical description | Colorless liquid with a mild, alcohol-like odor. | ||
|---|---|---|---|
| Boiling point | 207°F | Molecular weight | 60.1 |
| Freezing point/melting point | -196°F | Vapor pressure | 15 mmHg |
| Flash point | 72°F | Vapor density | |
| Specific gravity | 0.81 | Ionization potential | 10.15 eV |
| Lower explosive limit (LEL) | 2.2% | Upper explosive limit (UEL) | 13.7% |
| NFPA health rating | 1 | NFPA fire rating | 3 |
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2170 |
|---|---|
| Sampling group | OVSG-2 |
| Sampler/Sampling media | 2 Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of sorbent) connected in series [SKC 226-82], tube holder [SKC 222-3L-1], Type D cover [SKC 224-29D] |
| Sampling time* |
240 min |
| Sampling volume (TWA)* |
12 L |
| Sampling flow rate (TWA)* |
0.05 L/min |
| Sampling volume (STEL/Peak/C)* |
|
| Sampling flow rate (STEL/Peak/C)* |
|
| Analytical method instruments | GC-FID |
| Method reference | OSHA 5001 (fully validated) |
| Notes | Separate tubes and seal each after sampling. |
| Special requirements |
|
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media |
|
|---|---|
| Bulk Method |
|
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
200 ppm (500 mg/m³) |
REL-TWA |
200 ppm (500 mg/m³) |
TLV-TWA |
100 ppm [2006] |
PEL-TWA |
200 ppm (500 mg/m³) |
| PEL-STEL |
|
REL-STEL |
250 ppm (625 mg/m³) |
TLV-STEL |
|
PEL-STEL |
250 ppm (625 mg/m³) |
| PEL-C |
|
REL-C |
|
TLV-C |
|
PEL-C |
|
| Skin notation |
N |
Skin notation |
Y |
Skin notation |
N |
Skin notation |
Y |
| Notes: |
Notes:
|
Notes:
|
Notes:
|
||||
| Health factors: See NIH-NLM PubChem. | IDLH |
800 ppm |
|||||
| Carcinogenic classifications: TLV-A4 |
Notes:
|
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
|
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - N-Propanol NIOSH: Pocket Guide to Chemical Hazards - n-Propyl alcohol Literature References
|
Last Updated Date : 06/16/2023
ETHYL 2-CYANOACRYLATE
| CAS # | 7085-85-0 |
|---|---|
| Formula |
C₆H₇NO₂ |
| Synonyms |
2-cyanoacrylate acid, ethyl ester; ECA; ethyl cyanoacrylate; ethyl ⍺-cyanoacrylate; 2-propenoic acid, 2-cyano, ethyl ester |
| Physical description | Clear colorless liquid with irritating, sweet, ester-like odor | ||
|---|---|---|---|
| Boiling point | 54-56°C | Molecular weight | 125.14 |
| Freezing point/melting point | Vapor pressure | <2 mmHg at 25°C | |
| Flash point | Vapor density | ||
| Specific gravity | Ionization potential | ||
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | E108 |
|---|---|
| Sampling group | |
| Sampler/Sampling media | XAD-7 (80/40 mg sections, 20/60 mesh) coated with 10% phosphoric acid [SKC 226-98] |
| Sampling time* |
120 min |
| Sampling volume (TWA)* |
12 L |
| Sampling flow rate (TWA)* |
0.1 L/min |
| Sampling volume (STEL/Peak/C)* |
|
| Sampling flow rate (STEL/Peak/C)* |
|
| Analytical method instruments | HPLC |
| Method reference | OSHA 55 (fully validated) |
| Notes |
Samples must be kept at reduced temperature and shipped to lab cold. |
| Special requirements |
|
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media |
|
|---|---|
| Bulk Method |
|
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
|
REL-TWA |
|
TLV-TWA |
0.2 ppm [2017] |
PEL-TWA |
0.2 ppm (1.02 mg/m³) |
| PEL-STEL |
|
REL-STEL |
|
TLV-STEL |
1 ppm [2017] |
PEL-STEL |
|
| PEL-C |
|
REL-C |
|
TLV-C |
|
PEL-C |
|
| Skin notation |
NA |
Skin notation |
NA |
Skin notation |
N |
Skin notation |
N |
|
Notes:
Not established |
Notes:
Not established |
Notes:
dermal sensitization (DSEN), respiratory sensitization (RSEN) |
Notes:
|
||||
| Health factors: See NIH-NLM PubChem. | IDLH | ||||||
| Carcinogenic classifications: Not listed |
Notes:
|
||||||
|
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
|
|||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Not listed NIOSH: Pocket Guide to Chemical Hazards - Not listed Literature References
|
Last Updated Date : 12/19/2018