- Part Number:1910
- Part Number Title:Occupational Safety and Health Standards
- Subpart:1910 Subpart H
- Subpart Title:Hazardous Materials
- Standard Number:
- Title:Hydrogen.
- GPO Source:
General -
Definitions. As used in this section
Approved - Means, unless otherwise indicated, listed or approved by a nationally recognized testing laboratory. Refer to § 1910.7 for definition of nationally recognized testing laboratory.
Listed - See "approved".
DOT regulations - See § 1910.103 (a)(1)(v).
Scope -
Gaseous hydrogen systems.
Liquefied hydrogen systems.
Gaseous hydrogen systems -
Design -
Containers.
Designed, constructed, and tested in accordance with appropriate requirements of ASME Boiler and Pressure Vessel Code, section VIII - Unfired Pressure Vessels - 1968, which is incorporated by reference as specified in § 1910.6.
Each portable container shall be legibly marked with the name "Hydrogen" in accordance with the marking requirements set forth in § 1910.253(b)(1)(ii). Each manifolded hydrogen supply unit shall be legibly marked with the name "Hydrogen" or a legend such as "This unit contains hydrogen."
Safety relief devices.
Hydrogen containers shall be equipped with safety relief devices as required by the ASME Boiler and Pressure Vessel Code, section VIII Unfired Pressure Vessels, 1968 or the DOT Specifications and Regulations under which the container is fabricated.
Piping, tubing, and fittings.
Piping and tubing shall conform to section 2 - “Industrial Gas and Air Piping” - Code for Pressure Piping, ANSI B31.1-1967 with addenda B31.1-1969, which is incorporated by reference as specified in § 1910.6.
Equipment assembly.
Marking. The hydrogen storage location shall be permanently placarded as follows: “HYDROGEN - FLAMMABLE GAS - NO SMOKING - NO OPEN FLAMES,” or equivalent.
Testing. After installations, all piping, tubing, and fittings shall be tested and proved hydrogen gas tight at maximum operating pressure.
Location -
General.
Specific requirements.
The location of a system, as determined by the maximum total contained volume of hydrogen, shall be in the order of preference as indicated by Roman numerals in Table H-1.
Table H-1
Nature of location | Size of hydrogen system | ||
---|---|---|---|
Less than 3,000 CF | 3,000 CF to 15,000 CF | In excess of 15,000 CF | |
Outdoors | I | IDI. | |
In a separate building | II | II | II. |
In a special room | III | III | Not permitted. |
Inside buildings not in a special room and exposed to other occupancies | IV | Not permitted | Not permitted. |
The distances in Table H-2 Items 1 and 3 to 10 inclusive do not apply where protective structures such as adequate fire walls are located between the system and the exposure.
Table H-2
Type of outdoor exposure | Size of hydrogen system | |||
---|---|---|---|---|
Less than 3,000 CF | 3,000 CF to 15,000 CF | In excess of 15,000 CF | ||
1. Building or structure | Wood frame construction1 | 10 | 25 | 50 |
Heavy timber, noncombustible or ordinary construction1 | 0 | 10 | 225 | |
Fire-resistive construction1 | 0 | 0 | 0 | |
2. Wall openings | Not above any part of a system | 10 | 10 | 10 |
Above any part of a system | 25 | 25 | 25 | |
3. Flammable liquids above ground. | 0 to 1,000 gallons In excess of 1,000 gallons |
10 25 |
25 50 |
25 50 |
4. Flammable liquids below ground - 0 to 1,000 gallons | Tank Vent or fill opening of tank |
10 25 |
10 25 |
10 25 |
5. Flammable liquids below ground - in excess of 1,000 gallons. | Tank Vent or fill opening of tank |
20 25 |
20 25 |
20 25 |
6. Flammable gas storage, either high pressure or low pressure. | 0 to 15,000 CF capacity In excess of 15,000 CF capacity |
10 25 |
25 50 |
25 50 |
7. Oxygen storage | 12,000 CF or less4 | |||
More than 12,000 CF5 | ||||
8. Fast burning solids such as ordinary lumber, excelsior or paper | 50 | 50 | 50 | |
9. Slow burning solids such as heavy timber or coal | 25 | 25 | 25 | |
10. Open flames and other sources of ignition | 25 | 25 | 25 | |
11. Air compressor intakes or inlets to ventilating or air-conditioning equipment | 50 | 50 | 50 | |
12. Concentration of people3 | 25 | 50 | 50 |
1 Refer to NFPA No. 220 Standard Types of Building Construction for definitions of various types of construction. (1969 Ed.)
2 But not less than one-half the height of adjacent side wall of the structure.
3 In congested areas such as offices, lunchrooms, locker rooms, time-clock areas.
4 Refer to NFPA No. 51, gas systems for welding and cutting (1969).
5 Refer to NFPA No. 566, bulk oxygen systems at consumer sites (1969).
Design consideration at specific locations -
Outdoor locations.
Separate buildings.
Special rooms.
Operating instructions. For installations which require any operation of equipment by the user, legible instructions shall be maintained at operating locations.
Maintenance. The equipment and functioning of each charged gaseous hydrogen system shall be maintained in a safe operating condition in accordance with the requirements of this section. The area within 15 feet of any hydrogen container shall be kept free of dry vegetation and combustible material.
Liquefied hydrogen systems -
Design -
Containers.
Hydrogen containers shall comply with the following: Storage containers shall be designed, constructed, and tested in accordance with appropriate requirements of the ASME Boiler and Pressure Vessel Code, section VIII - Unfired Pressure Vessels (1968) or applicable provisions of API Standard 620, Recommended Rules for Design and Construction of Large, Welded, Low-Pressure Storage Tanks, Second Edition (June 1963) and appendix R (April 1965), which is incorporated by reference as specified in § 1910.6.
Supports. Permanently installed containers shall be provided with substantial noncombustible supports securely anchored on firm noncombustible foundations. Steel supports in excess of 18 inches in height shall be protected with a protective coating having a 2-hour fire-resistance rating.
Marking. Each container shall be legibly marked to indicate “LIQUEFIED HYDROGEN - FLAMMABLE GAS.”
Safety relief devices.
Stationary liquefied hydrogen containers shall be equipped with safety relief devices sized in accordance with CGA Pamphlet S-1, part 3, Safety Relief Device Standards for Compressed Gas Storage Containers, which is incorporated by reference as specified in § 1910.6.
Portable liquefied hydrogen containers complying with the U.S. Department of Transportation Regulations shall be equipped with safety relief devices as required in the U.S. Department of Transportation Specifications and Regulations. Safety relief devices shall be sized in accordance with the requirements of CGA Pamphlet S-1, Safety Relief Device Standards, part 1, Compressed Gas Cylinders and part 2, Cargo and Portable Tank Containers.
Piping, tubing, and fittings.
Gaseous hydrogen piping and tubing (above −20 °F.) shall conform to the applicable sections of Pressure Piping section 2 - Industrial Gas and Air Piping, ANSI B31.1-1967 with addenda B31.1-1969. Design of liquefied hydrogen or cold (−20 °F. or below) gas piping shall use Petroleum Refinery Piping ANSI B31.3-1966 or Refrigeration Piping ANSI B31.5-1966 with addenda B31.5a-1968 as a guide, which are incorporated by reference as specified in § 1910.6.
Means shall be provided to minimize exposure of personnel to piping operating at low temperatures and to prevent air condensate from contacting piping, structural members, and surfaces not suitable for cryogenic temperatures. Only those insulating materials which are rated nonburning in accordance with ASTM Procedures D1692-68, which is incorporated by reference as specified in § 1910.6, may be used. Other protective means may be used to protect personnel. The insulation shall be designed to have a vapor-tight seal in the outer covering to prevent the condensation of air and subsequent oxygen enrichment within the insulation. The insulation material and outside shield shall also be of adequate design to prevent attrition of the insulation due to normal operating conditions.
Equipment assembly.
Testing.
Liquefied hydrogen vaporizers.
Electrical systems.
Bonding and grounding. The liquefied hydrogen container and associated piping shall be electrically bonded and grounded.
Location of liquefied hydrogen storage -
General requirements.
When locating liquified hydrogen storage containers near above-ground flammable liquid storage or liquid oxygen storage, it is advisable to locate the liquefied hydrogen container on ground higher than flammable liquid storage or liquid oxygen storage.
Storage sites shall be fenced and posted to prevent entrance by unauthorized personnel. Sites shall also be placarded as follows: “Liquefied Hydrogen - Flammable Gas - No Smoking - No Open Flames.”
If liquified hydrogen is located in (as specified in Table H-3) a separate building, in a special room, or inside buildings when not in a special room and exposed to other occupancies, containers shall have the safety relief devices vented unobstructed to the outdoors at a minimum elevation of 25 feet above grade to a safe location as required in paragraph (c)(1)(iv)(b) of this section.
Specific requirements.
The location of liquefied hydrogen storage, as determined by the maximum total quantity of liquified hydrogen, shall be in the order of preference as indicated by Roman numerals in the following Table H-3.
Table H-3 - Maximum Total Quantity of Liquefied Hydrogen Storage Permitted
Nature of location | Size of hydrogen storage (capacity in gallons) | |||
---|---|---|---|---|
39.63 (150 liters) to 50 | 51 to 300 | 301 to 600 | In excess of 600 | |
Outdoors | I | I | I | I. |
In a separate building | II | II | II | Not permitted. |
In a special room | III | III | Not permitted | Do. |
Inside buildings not in a special room and exposed to other occupancies | IV | Not permitted | ......do | Do. |
Note: This table does not apply to the storage in dewars of the type generally used in laboratories for experimental purposes.
The minimum distance in feet from liquefied hydrogen systems of indicated storage capacity located outdoors, in a separate building, or in a special room to any specified exposure shall be in accordance with Table H-4.
Table H-4 - Minimum Distance (Feet) From Liquefied Hydrogen Systems to Exposure1 2
Type of exposure | Liquefied hydrogen storage (capacity in gallons) | ||
---|---|---|---|
39.63 (150 liters) to 3,500 | 3,501 to 15,000 | 15,001 to 30,000 | |
1. Fire-resistive building and fire walls3 | 5 | 5 | 5 |
2. Noncombustible building3 | 25 | 50 | 75 |
3. Other buildings3 | 50 | 75 | 100 |
4. Wall openings, air-compressor intakes, inlets for air-conditioning or ventilating equipment | 75 | 75 | 75 |
5. Flammable liquids (above ground and vent or fill openings if below ground) (see 513 and 514) | 50 | 75 | 100 |
6. Between stationary liquefied hydrogen containers | 5 | 5 | 5 |
7. Flammable gas storage | 50 | 75 | 100 |
8. Liquid oxygen storage and other oxidizers (see 513 and 514) | 100 | 100 | 100 |
9. Combustible solids | 50 | 75 | 100 |
10. Open flames, smoking and welding | 50 | 50 | 50 |
11. Concentrations of people | 75 | 75 | 75 |
1 The distance in Nos. 2, 3, 5, 7, 9, and 12 in Table H-4 may be reduced where protective structures, such as firewalls equal to height of top of the container, to safeguard the liquefied hydrogen storage system, are located between the liquefied hydrogen storage installation and the exposure.
2 Where protective structures are provided, ventilation and confinement of product should be considered. The 5-foot distance in Nos. 1 and 6 facilitates maintenance and enhances ventilation.
3 Refer to Standard Types of Building Construction, NFPA No. 220-1969 for definitions of various types of construction.
In congested areas such as offices, lunchrooms, locker rooms, time-clock areas.
Handling of liquefied hydrogen inside buildings other than separate buildings and special rooms. Portable liquefied hydrogen containers of 50 gallons or less capacity as permitted in Table H-3 and in compliance with subdivision (i)(f) of this subparagraph when housed inside buildings not located in a special room and exposed to other occupancies shall comply with the following minimum requirements:
Design considerations at specific locations -
Outdoor locations.
If protective walls are provided, they shall be constructed of noncombustible materials and in accordance with the provisions of paragraph (c)(3)(i)(a) of this section.
Electrical wiring and equipment shall comply with paragraph (c)(1)(ix) (a) and (b) of this section.
Separate buildings.
Electrical wiring and equipment shall comply with paragraphs (c)(1)(ix) (a) and (b) of this section except that the provisions of paragraph (c)(1)(ix)(b) of this section shall apply to all electrical wiring and equipment in the separate building.
Special rooms.
Floors, walls, and ceilings shall have a fire resistance rating of at least 2 hours. Walls or partitions shall be continuous from floor to ceiling and shall be securely anchored. At least one wall shall be an exterior wall. Openings to other parts of the building shall not be permitted. Windows and doors shall be in exterior walls and doors shall be located in such a manner that they will be accessible in an emergency. Windows shall be of shatterproof glass or plastic in metal frames.
Ventilation shall be as provided in paragraph (c)(3)(ii)(b) of this section.
Explosion venting shall be provided in exterior walls or roof only. The venting area shall be equal to not less than 1 square foot per 30 cubic feet of room volume and may consist of any one or any combination of the following: Walls of light noncombustible material; lightly fastened hatch covers; lightly fastened swinging doors opening outward in exterior walls; lightly fastened walls or roofs designed to relieve at a maximum pressure of 25 pounds per square foot.
There shall be no sources of ignition.
Electrical wiring and equipment shall comply with paragraph (c)(1)(ix) (a) and (b) of this section except that the provision of paragraph (c)(1)(ix)(b) of this section shall apply to all electrical wiring and equipment in the special room.
Operating instructions -
Written instructions. For installation which require any operation of equipment by the user, legible instructions shall be maintained at operating locations.
Attendant. A qualified person shall be in attendance at all times while the mobile hydrogen supply unit is being unloaded.
Security. Each mobile liquefied hydrogen supply unit used as part of a hydrogen system shall be adequately secured to prevent movement.
Grounding. The mobile liquefied hydrogen supply unit shall be grounded for static electricity.
Maintenance. The equipment and functioning of each charged liquefied hydrogen system shall be maintained in a safe operating condition in accordance with the requirements of this section. Weeds or similar combustibles shall not be permitted within 25 feet of any liquefied hydrogen equipment.
[39 FR 23502, June 27, 1974, as amended at 43 FR 49746, Oct. 24, 1978; 53 FR 12121, Apr. 12, 1988; 55 FR 32015, Aug 6, 1990; 58 FR 35309, June 30, 1993; 61 FR 9236, March 7, 1996; 69 FR 31881, June 8, 2004; 72 FR 71069, Dec. 14, 2007]