CARBON MONOXIDE†
CAS # | 630-08-0 |
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Formula |
CO |
Synonyms |
carbon oxide; flue gas; monoxide; carboxyhemoglobin/COHb |
Physical description | Colorless, odorless gas. | ||
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Boiling point | -313°F | Molecular weight | 28.0 |
Freezing point/melting point | -337°F | Vapor pressure | >35 atm |
Flash point | Vapor density | 0.97 | |
Specific gravity | 0.791 at -312.7°F | Ionization potential | 14.01 eV |
Lower explosive limit (LEL) | 12.5% | Upper explosive limit (UEL) | 74% |
NFPA health rating | 3 | NFPA fire rating | 4 |
NFPA reactivity rating | 0 | NFPA special instruction | |
Vapor hazard ratio (VHR) | |||
Historical exceedance percentage | |||
Target organs |
Analyte code (IMIS no.) | 0560 | 0560 | C730 (COHb) |
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Sampling group | |||
Sampler/Sampling media | Dräger X-am 5600 Multi-Gas Detector with a Dräger XXS CO LC electrochemical sensor. | Five layer aluminized gas sampling bag [Calibrated Instruments GSB-P/10] | |
Sampling time* | Contact the SLTC Physical Measurements Team Leader in cases where CO poisoning affects more than 4 individuals. The most practical use of resources sometimes requires evaluating the most severely affected employees. |
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Sampling volume (TWA)* | 2-5 L |
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Sampling flow rate (TWA)* | 0.01-0.05 L/min |
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Sampling volume (STEL/Peak/C)* | 2-5 L |
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Sampling flow rate (STEL/Peak/C)* | 0.3 L/min |
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Analytical method instruments | GC-DID | ||
Method reference | OSHA 1026 (fully validated) | OSHA ID-210 (fully validated) | |
Notes | If nitric oxide (NO) is present at the monitoring site, please notify the OTC when requesting a monitoring kit and each provided gas monitor will be equipped with both CO and NO sensors. Do not use this method when hydrogen, acetylene, or ethene are present. |
Use detector tubes for screening. If greater than PEL, order gas sampling bags. *Note for sampling with Cali-5-BondTM, 10 liter, five layer aluminized gas sampling bag: This gas sampling bag has an integrated twist on/off valve (V-NPB-2/00) Septum (A-SEPT/.750). The nickel-plated brass connection allows the user to control gas flow into or out of the bag by twisting the barbed stem open (counterclockwise) or closed (clockwise). The jagged barb firmly secures 3/16″ ID sample tubing to the stem of the valve. |
COHb analysis is a routine measurement during the medical response to a suspected CO-poisoning incident or from an autopsy after a suspected CO-poisoning incident. As a result, the COHb analysis is performed using a blood-gas instrument that is part of a quality system. The COHb analysis is not performed at the SLTC. Carbon monoxide (CO) exposure is determined by calculation based on carboxyhemoglobin (COHb) measurements provided by medical professionals as described below. OSHA uses a modified Coburn, Forster, Kane (CFK) Calculation. The documented SLTC modifications (printed in the supplemental report that accompanies the results) use a more accurate version of the CFK equation than the closed-form [e.g., ppm CO = f(x,y,z,...)] version used in the 1972 NIOSH criteria document for the purpose of calculating the 8-hr TWA ppm REL that would result in a 5% COHb level [U.S. Department of Health, Education, and Welfare: Criteria for a Recommended Standard - Occupational Exposure to Carbon Monoxide. Pub. No. HSM 73-11000. NIOSH, Cincinnati, OH (1972).] The calculation also provides an incident-specific sampling and analytical error (SAE) based on a Monte-Carlo approach designed to deal with the uncertainties in the data. The calculation is performed at the SLTC and the results are critically assessed for correctness by the SLTC experts prior to reporting. The SLTC is available to assist the CSHO with acquiring the data and interpreting the results. |
Special requirements | The exposure incident is documented on a worksheet. Personal information is used to assess the affect of any tobacco smoking behavior (before, during and after the exposure), blood volume, and activity levels (during and after the exposure). Post-exposure delay to sampling is preferable less than approx 6 hours for living persons. Longer delays may result in significantly higher SAEs or the inability to distinguish an overexposure from baseline for an individual. Contact Scott Jones at 801-233-4962 [OSHA staff only]. For further information please enroll in the Carboxyhemoglobin (COHb) training resource in course mill “TR_CO Calculated from Carboxyhemoglobin”. |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
Wipe Sampler/Sampling media | |
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Bulk Method |
Device | CMS Chip | Single Gas Detector | Single Gas Detector | Single Gas Detector | Single Gas Detector | Single Gas Detector |
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Model/Type | Carbon monoxide, 5-150 ppm range | BW Solo (BWS1 CO) | Dräger Pac 6500 CO (8327614) | Dräger Pac 7000 CO (8318970) | GasBadge Pro (1810-0060) | ToxiRAE Pro (G02-BF10-100) |
Sampling information (see manufacturer instructions) |
Honeywell Safety | Dräger Portable Gas Detection | Dräger Portable Gas Detection | Industrial Scientific | Honeywell Safety |
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
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PEL-TWA |
50 ppm (55 mg/m³) |
REL-TWA |
35 ppm (40 mg/m³) |
TLV-TWA | PEL-TWA |
25 ppm (29 mg/m³) |
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PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL |
200 ppm |
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PEL-C | REL-C |
200 ppm (229 mg/m³) |
TLV-C | PEL-C | |||
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Notes: | Notes: |
Notes:
Visit the ACGIH TLV site for specific data |
Notes: | ||||
Health factors: See NIH-NLM PubChem. | IDLH |
1200 ppm |
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Carcinogenic classifications: Not listed | Notes: | ||||||
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
200 ppm/350 ppm/500 ppm |
Additional Resources and Literature References
NOAA: CAMEO Chemicals - Carbon monoxide NIOSH: Pocket Guide to Chemical Hazards - Carbon monoxide Literature References
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Last Updated Date : 11/01/2024