NICKEL CARBONYL†
Chemical Identification | |
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CAS # | 13463-39-3 |
Formula |
Ni(CO)₄ |
Synonyms |
nickel tetracarbonyl; tetracarbonyl nickel |
Physical Properties | |||
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Physical description | Colorless to yellow liquid with a musty odor. | ||
Boiling point | 110°F | Molecular weight | 170.75 |
Freezing point/melting point | -2.2°F | Vapor pressure | 315 mmHg |
Flash point | <-11.2°F | Vapor density | 5.89 |
Specific gravity | 1.32 at 63°F | Ionization potential | 8.28 eV |
Lower explosive limit (LEL) | 2% | Upper explosive limit (UEL) | |
NFPA health rating | 4 | NFPA fire rating | 3 |
NFPA reactivity rating | 3 | NFPA special instruction | |
Vapor hazard ratio (VHR) | |||
Historical exceedance percentage | |||
Target organs |
Monitoring Methods Used by OSHA | ||||||
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Analyte code (IMIS no.) | ||||||
Sampling group | ||||||
Sampler/Sampling media | ||||||
Sampling time* | ||||||
Sampling volume (TWA)* | ||||||
Sampling flow rate (TWA)* | ||||||
Sampling volume (STEL/Peak/C)* | ||||||
Sampling flow rate (STEL/Peak/C)* | ||||||
Analytical method instruments | ||||||
Method reference | ||||||
Notes | ||||||
Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
Wipe Method | |
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Sampler/Sampling media |
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Bulk Method |
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On-Site Screening Techniques | ||||||
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Device | ||||||
Model/Type | ||||||
Sampling information (see manufacturer instructions) |
Exposure Limits | |||||||
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OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
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PEL-TWA |
0.001 ppm (0.007 mg/m³) |
REL-TWA |
0.001 ppm (0.007 mg/m³) |
TLV-TWA |
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PEL-TWA |
0.001 ppm (0.007 mg/m³) |
PEL-STEL |
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REL-STEL |
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TLV-STEL |
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PEL-STEL |
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PEL-C |
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REL-C |
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TLV-C |
0.05 mg/m³ [2013] |
PEL-C |
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Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Notes: |
Notes:
CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens. |
Notes:
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Notes:
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Health factors: See NIH-NLM PubChem. | IDLH |
2 ppm |
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Carcinogenic classifications: IARC-1, NIOSH-Ca, NTP-K, EPA-B2, TLV-A3 |
Notes:
Ca |
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AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
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Additional Resources and Literature References |
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NOAA: CAMEO Chemicals - Nickel carbonyl NIOSH: Pocket Guide to Chemical Hazards - Nickel carbonyl Literature References
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Last Updated Date : 01/28/2021