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SEC-HEXYL ACETATE†
| CAS # | 108-84-9 | 
|---|---|
| Formula | C₈H₁₆O₂ | 
| Synonyms | 1,3-dimethylbutyl acetate; methylamyl acetate; methylisoamyl acetate | 
| Physical description | Colorless liquid with a mild, pleasant, fruity odor. | ||
|---|---|---|---|
| Boiling point | 297°F | Molecular weight | 144.22 | 
| Freezing point/melting point | -83°F | Vapor pressure | 3 mmHg | 
| Flash point | 113°F | Vapor density | |
| Specific gravity | 0.86 | Ionization potential | |
| Lower explosive limit (LEL) | 0.9% (calc) | Upper explosive limit (UEL) | 5.7% (calc) | 
| NFPA health rating | 1 | NFPA fire rating | 2 | 
| NFPA reactivity rating | 0 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1387 | 
|---|---|
| Sampling group | |
| Sampler/Sampling media | CSC tube (100/50 mg) [SKC 226-01] | 
| Sampling time* | |
| Sampling volume (TWA)* | 1-10 L | 
| Sampling flow rate (TWA)* | 0.01-0.2 L/min | 
| Sampling volume (STEL/Peak/C)* | |
| Sampling flow rate (STEL/Peak/C)* | |
| Analytical method instruments | GC-FID | 
| Method reference | NIOSH 1450 (fully validated) | 
| Notes | |
| Special requirements | 
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | |
|---|---|
| Bulk Method | 
| Device | Infrared spectrophotometer | Infrared spectrophotometer | 
|---|---|---|
| Model/Type | Miran 1A & 1B | Miran 103 | 
| Sampling information (see manufacturer instructions) | 0.3 ppm @ 9.6 µm | 0-50 ppm@9.6 µm | 
| 
                                  OSHA PEL 8-hour TWA (ST) STEL (C) Ceiling Peak | 
                                  NIOSH REL Up to 10-hour TWA (ST) STEL (C) Ceiling | 
                                  ACGIH TLV© 8-hour TWA (ST) STEL (C) Ceiling | |||||
|---|---|---|---|---|---|---|---|
| PEL-TWA | 50 ppm (300 mg/m³) | REL-TWA | 50 ppm (300 mg/m³) | TLV-TWA | 50 ppm [1963] | PEL-TWA | 50 ppm (300 mg/m³) | 
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation | N | Skin notation | N | Skin notation | N | Skin notation | N | 
| Notes: | Notes: | Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | 500 ppm | |||||
| Carcinogenic classifications: Not listed | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
| NOAA: CAMEO Chemicals - Methylamyl acetate NIOSH: Pocket Guide to Chemical Hazards - sec-Hexyl acetate Literature References 
 | 
Last Updated Date : 01/28/2021
