P-PHENYLENEDIAMINE†

Chemical Identification
Chemical Identification
CAS # 106-50-3
Formula

C₆H₈N₂

Synonyms
Physical Properties
Physical Properties
Physical description White to slightly red, crystalline solid.
Boiling point 513°F Molecular weight 108.15
Freezing point/melting point 295°F Vapor pressure <1 mmHg
Flash point 312°F Vapor density 3.72
Specific gravity Ionization potential 6.89 eV
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs
Monitoring Methods Used by OSHA
Monitoring Methods Used by OSHA
Analyte code (IMIS no.) 2042
Sampling group
Sampler/Sampling media 2 GFFs (37 mm) coated with sulfuric acid, in 3-piece cassette, separated by the ring section [SKC 225-9004]
Sampling time*
Sampling volume (TWA)*

100 L

Sampling flow rate (TWA)*

1 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments HPLC
Method reference OSHA 87 (fully validated)
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Wipe Method
Wipe Method
Sampler/Sampling media

Wipe with GFF (37 mm), Type A/E [AP4003705].

Bulk Method
Bulk Method

Limit the amount of bulk submitted to 1 g or 1 mL.

On-Site Screening Techniques
On-Site Screening Techniques
Device
Model/Type
Sampling information
(see manufacturer instructions)
Exposure Limits
Exposure Limits
OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.1 mg/m³

REL-TWA

0.1 mg/m³

TLV-TWA

0.1 mg/m³ [1988]

PEL-TWA

0.1 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

Y

Skin notation

Y

Skin notation

Y

Skin notation

Y

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes: Notes:
Health factors:  See NIH-NLM PubChem. IDLH

25 mg/m³

Carcinogenic classifications: TLV-A4, IARC-3 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
Additional Resources and Literature References
Additional Resources and Literature References

NOAA: CAMEO Chemicals - P-Phenylenediamine

NIOSH: Pocket Guide to Chemical Hazards - p-Phenylene diamine

Literature References

  • ACGIH: Documentation of the Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) - p-Phenylenediamine. See annual publication for most recent information.

Last Updated Date : 01/08/2021