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MESITYL OXIDE†
| CAS # | 141-79-7 | 
|---|---|
| Formula | C₆H₁₀O | 
| Synonyms | isobutenyl methyl ketone; isopropylideneacetone; methyl isobutenyl ketone; 4-methyl-3-penten-2-one | 
| Physical description | Oily, colorless to light-yellow liquid with a peppermint- or honey-like odor. | ||
|---|---|---|---|
| Boiling point | 266°F | Molecular weight | 98.2 | 
| Freezing point/melting point | -52°F | Vapor pressure | 9 mmHg | 
| Flash point | 87°F | Vapor density | |
| Specific gravity | 0.853 at 68°F | Ionization potential | 9.08 eV | 
| Lower explosive limit (LEL) | 1.4% | Upper explosive limit (UEL) | 7.2% | 
| NFPA health rating | 3 | NFPA fire rating | 3 | 
| NFPA reactivity rating | 1 | NFPA special instruction | |
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1635 | 
|---|---|
| Sampling group | |
| Sampler/Sampling media | CSC tube (100/50 mg) [SKC 226-01] | 
| Sampling time* | |
| Sampling volume (TWA)* | 1-25 L | 
| Sampling flow rate (TWA)* | 0.01-0.2 L/min | 
| Sampling volume (STEL/Peak/C)* | 
 | 
| Sampling flow rate (STEL/Peak/C)* | 
 | 
| Analytical method instruments | GC-FID | 
| Method reference | NIOSH 1301 (fully validated) | 
| Notes | 
 | 
| Special requirements | 
 | 
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | 
 | 
|---|---|
| Bulk Method | 
 | 
| Device | Detector tube | Infrared spectrophotometer | 
|---|---|---|
| Model/Type | Matheson-Kitagawa 8014-190U | Miran 1A & 1B | 
| Sampling information (see manufacturer instructions) | 5-100 ppm range | 0.8 ppm@8.2 µm | 
| 
                                  OSHA PEL 8-hour TWA (ST) STEL (C) Ceiling Peak | 
                                  NIOSH REL Up to 10-hour TWA (ST) STEL (C) Ceiling | 
                                  ACGIH TLV© 8-hour TWA (ST) STEL (C) Ceiling | |||||
|---|---|---|---|---|---|---|---|
| PEL-TWA | 25 ppm (100 mg/m³) | REL-TWA | 10 ppm (40 mg/m³) | TLV-TWA | 15 ppm [1992] | PEL-TWA | 15 ppm (60 mg/m³) | 
| PEL-STEL | 
 | REL-STEL | 
 | TLV-STEL | 25 ppm [1992] | PEL-STEL | 25 ppm (100 mg/m³) | 
| PEL-C | 
 | REL-C | 
 | TLV-C | 
 | PEL-C | 
 | 
| Skin notation | N | Skin notation | N | Skin notation | N | Skin notation | N | 
| Notes: | Notes: 
 | Notes: 
 | Notes: 
 | ||||
| Health factors: See NIH-NLM PubChem. | IDLH | 1400 ppm | |||||
| Carcinogenic classifications: Not listed | Notes: 10 % of LEL | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: 
 | |||||||
Additional Resources and Literature References
| NOAA: CAMEO Chemicals - Mesityl oxide NIOSH: Pocket Guide to Chemical Hazards - Mesityl oxide Literature References 
 | 
Last Updated Date : 01/04/2021
