CAPTAN

Chemical Identification
Chemical Identification
CAS # 133-06-2
Formula

C₉H₈Cl₃NO₂S

Synonyms

captane; N-trichloromethylmercapto-4-cyclohexene-1,2-dicarboximide; Merpan; Orthocide; Pillarcap

Physical Properties
Physical Properties
Physical description Odorless, white, crystalline powder.
Boiling point decomposes Molecular weight 300.6
Freezing point/melting point 352°F Vapor pressure 0 mmHg (approx)
Flash point Vapor density
Specific gravity 1.74 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs
Monitoring Methods Used by OSHA
Monitoring Methods Used by OSHA
Analyte code (IMIS no.) 0529
Sampling group
Sampler/Sampling media OSHA versatile sampler (OVS-2) - 13 mm XAD-2 tube (270/140 mg) with GFF enclosed [SKC 226-30-16]
Sampling time*
Sampling volume (TWA)*

60 L

Sampling flow rate (TWA)*

1 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments HPLC-UV
Method reference OSHA PV2093 (partially validated)
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Wipe Method
Wipe Method
Sampler/Sampling media

Wipe with GFF (37 mm), Type A/E [AP4003705]

Bulk Method
Bulk Method

Limit the amount of bulk submitted to 1 g or 1 mL.

On-Site Screening Techniques
On-Site Screening Techniques
Device
Model/Type
Sampling information
(see manufacturer instructions)
Exposure Limits
Exposure Limits
OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA REL-TWA

5 mg/m³

TLV-TWA

5 mg/m³ (inhalable particulate matter) [1999]

PEL-TWA

5 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

NA

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

Not established

Notes:

CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A

Notes:

dermal sensitizer (DSEN)

Notes:
Health factors:  See NIH-NLM PubChem. IDLH
Carcinogenic classifications: IARC-3, NIOSH-Ca, TLV-A3 Notes:

Ca

AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
Additional Resources and Literature References
Additional Resources and Literature References

NOAA: CAMEO Chemicals - Captan

NIOSH: Pocket Guide to Chemical Hazards - Captan

Literature References

  • ACGIH: Documentation of the Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) - Captan. See annual publication for most recent information.

Last Updated Date : 12/21/2020