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Hair Salons OSHA has issued an updated hazard alert on formaldehyde dangers to hair salon owners and workers after new agency findings and FDA warning letter. See press release.
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Formaldehyde in Your Products
Name-Brand Products Containing Formaldehyde

OSHA has identified several brand-name products that contain formaldehyde or that can expose you to formaldehyde during use, even though they do not list formaldehyde on their labels or MSDSs:

Brazilian Blowout

Bottles of Brazilian Blowout Acai Smoothing Solution and Brazilian Blowout Professional Smoothing Solution must have "CAUTION" stickers on the bottles to warn users of potential exposure to formaldehyde gas and the need for precautionary measures. Formaldehyde or methylene glycol must also be prominently identified in an ingredient list on the bottle. These actions are part of a settlement reached between the distributer, GIB LLC, and the State of California that was announced on January 30, 2012.

  • Acai Professional Smoothing Solution (FDA Warning Letter)
  • Professional Brazilian Blowout Solution

Cadiveu

  • Brasil Cacau
  • Acai Therapy

Copomon/Coppola

  • Keratin Complex Smoothing Therapy
    • Natural Keratin Smoothing Treatment
    • Natural Keratin Smoothing Treatment Blonde
    • Express Blow Out

Marcia Teixeira

  • Brazilian Keratin Treatment
  • Advanced Treatment
  • Chocolate Treatment
  • Soft Treatment
  • Soft Chocolate Treatment

Oregon OSHA's report on Hair Smoothing Products [209 KB PDF, 34 pages] and ChemRisk, LLC's journal article include the names of additional products that have been shown to contain formaldehyde.

OSHA has found that many hair smoothing products contain formaldehyde, formaldehyde dissolved in water (called methylene glycol), or other chemicals that can release formaldehyde during use. Using products that contain these substances can result in worker exposure to unsafe levels of formaldehyde.  In three salons, Federal OSHA found that stylists using either Brazilian Blowout Acai Professional Smoothing Solution or Cadiveu Brasil Cacau were exposed to formaldehyde above OSHA's 15-minute short term exposure limit (STEL) of 2 parts formaldehyde per million parts of air (ppm).  In one salon, formaldehyde levels during the blow drying phase of treatment were measured at 10 ppm - five times the OSHA STEL.

It can be difficult to tell which hair smoothing products contain or can release formaldehyde. Even products that do not list formaldehyde or methylene glycol on the label, or that claim to be "formaldehyde free" or "no formaldehyde," can still expose workers to formaldehyde.

It is important to know how to find out if products used in your salon can expose workers to formaldehyde, and what you should do if your salon or beauty school uses products that might expose workers.

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Product Labels and Material Safety Data Sheets (MSDS)

OSHA's Hazard Communication and formaldehyde standard require formaldehyde and other substances that can lead to formaldehyde exposure to be listed in two places for products: on the label on the product bottle or box and in the product's material safety data sheets (MSDSs), which are documents that explain the health hazards of products that contain hazardous chemicals and the recommended safe practices for working with them.

If a product contains 0.1% or more formaldehyde or releases at least 0.1 ppm of it into the air, manufacturers, importers, and distributors must include the following on the label:

  • Notice that the product contains formaldehyde or may release formaldehyde.
  • Name and address of the manufacturer, importer, and/or other responsible companies.
  • Notice that employers and MSDS can provide additional hazard information.

If a product can release more than 0.5 ppm of formaldehyde into the air, the label must also include:

  • A list of all product health and safety hazards
  • The words "Potential Cancer Hazard”

The MSDS provides more information about product hazards than the product label does. The MSDSs for hair smoothing products must be available to workers in the salon. OSHA's formaldehyde standard and hazard communication standard require a product's MSDS to list:

  • Name of the product used on the label.

  • Common names of all hazardous chemicals that make up 1% or more of the product.

  • Common names of all ingredients that can cause cancer (including formaldehyde) and that make up 0.1% or more of the product.

  • Common names of all hazardous chemicals that could be released into the air above OSHA or American Conference of Governmental Industrial Hygienists established limits.

  • Common names of hazardous ingredients that could be released that could be released into the air at levels that would pose a health risk for employees (0.1 ppm for formaldehyde).

  • Health and safety information for each listed hazardous chemical, including health hazards.

  • Common ways that people are exposed to the product and its hazardous ingredients.

  • Limits of how much of each hazardous ingredient can be in the air adopted by OSHA, the American Conference of Governmental Industrial Hygienists, and the manufacturer.

  • Notice of whether the chemical is considered a cancer-causing substance by OSHA, the International Agency for Cancer Research, or the National Toxicology Program.

  • How to safely store and use the product, including what protective equipment to wear and what to do in an emergency, including first aid.

  • The name, address, and telephone number of the company or person responsible for preparing the MSDS, and the date it was made or last changed.
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Chemicals that Can Release Formaldehyde

Just because the name "formaldehyde" or the name methylene glycol is not on a product label or MSDS does not mean the product cannot expose workers to formaldehyde. Sometimes, manufacturers or distributors intentionally omit ingredients from labels or MSDS. There are also other names for formaldehyde, and other chemicals that can expose you to formaldehyde when the product is used. These are listed in the table below, and are subject to the same OSHA rules as formaldehyde.

Chemicals That Can Release Formaldehyde1

Chemical Name

Synonym

CAS Number

Formaldehyde Formalin
Methanal
50-00-0
Methylene glycol Methanediol
formalin
formaldehyde monohydrate
463-57-0
Timonacic acid thiazolidinecarboxylic acid, 1,3-thiazolidine-4-carboxylic acid 60731-25-1
(Phenylmethoxy)methanol Benzylhemiformal
benzyloxymethanol
phenylmethoxymethanol
Preventol D2
14548-60-8
7a-ethyldihydro-1H, 3H,5H-oxazolo[3,4-c]oxazole Bioban CS-1246
ethyldihydrooxazolo[3,4-c]-oxazole
5-ethyl-1-aza-3,7-dioxa-bi-cyclo[3.3.0]octane
7747-35-5
Mixture of:
4-(2-nitrobutyl)morpholine and
4,4’-(2-ethyl-2-nitro-1,3-propanediyl)bismorpholine
Bioban P-1487
Mixture of:
nitrobutylmorpholine and
ethylnitrotrimethylenedimorpholine
37301-88-4
2224-44-4
1854-23-5
5-bromo-5-nitro-1,3-dioxane Bromonitrodioxane
Bronidox
30007-47-7
2-bromo-2-nitro-1,3-propanediol Bromonitropropanediol
Bronopol
52-51-7
N-(3-chloroallyl)hexamethylene-tetraminiumchloride Chloroallylhexaminium chloride
3-chloroallyl hexaminiumchloride
Dowicil 75
Dowicil 200
Quaternium 15
4080-31-3
cis(51229-78-8)
N-(1,3-bis(hydroxymethyl)2-5-dioxo-4-imidiazolidinyl)-N,N’-bis(hydroxymethyl)urea Diazolidinyl urea
tetramethylol hydanotin urea
Germaben II
Germall II
78491-02-8
Dimethoxymethane Formal
methylal
109-87-8
Formaldehyde, polymer with dimethyl-2,4-imidazolidinedione Dimethylhydantoin formaldehyde resin
DMHF
9065-13-8
N,N’-bis(hydroxymethyl)urea Dimethylol urea
dihydroxymethylurea
dimethylurea
urea formaldehyde
140-95-4
1,3-bis(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidinedione DMDM hydantoin
dimethyloldimethylhydantoin
1,3-dimethylol-5,5-dimethylhydantoin
DMDMH
Glydant
6440-58-0
Mixture of:
1,3,5-triethylhexahydro-1,3,5-triazine
1,3,5-triazine-1,3,5(2H,4H,6H) triethanol
Forcide 78
Mixture of:
Triethylhexahydro s-triazine and
trihydroxyethylhexahydro s-triazine
91925-30-3
7779-27-3
4719-04-4
1,3,5,7-tetraazatricyclo(3.3.1.1) decane Hexamethylenetetramine
hexamine
methenamine
Urotropine
100-97-0
2,4-imidazolidinedione Hydantoin
glycolylurea
461-72-3
N,N"-methylenebis(N’-(3-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl)urea) Imidazolidinyl urea
bis(methylolhydantoin urea) methane
Euxyl K 200
Germall 115
39236-46-9
Hydroxymethly-5,5-dimethyl-2,4-imidazolidinedione MDM hydantoin
monomethyloldimethylhydanotin
Dantoin 685
MDMH
27636-82-4
1-hydroxymethyl-5,5-dimethyl-2,4-imidazolidinedione   116-25-6
3-hydroxymethyl-5,5-dimethyl-2,4-imidazolidinedione   16228-00-5
3,3’-methylenebis(5-methyloxazolidine) N,N’methylenebis(5-methyloxazolidine)
Grotan OX
66204-44-2
2-chloro-N-(hydroxymethyl)-acetamide N-methylolchloracetamide
Grotan HD
Parmetol K50
Preventol D3
Preventol D5
2832-19-1
2-(hydroxymethylamino)ethanol N-methylolethanolamine 34375-28-5
Paraformaldehyde Polyoxymethylene 30525-89-4
1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol Trihydroxyethylhexahydro s-triazine
Grotan BK
KM 200
4719-04-4
2-(hydroxymethyl)-2-nitro-1,3-propanediol Tris(hydroxymethyl)nitromethane
trimethylolnitromethane
126-11-4
1Adapted From: Fyvholm, MA, Andersen, P (1993): Identification of Formaldehyde Releasers and Occurrence of Formaldehyde and Formaldehyde Releasers in Registered Chemical Products. American Journal of Industrial Medicine 24(5):533-52.

Note: This list may not include all formaldehyde releasing chemicals

Knowing how to read and understand labels and MSDSs is important to protecting worker health.

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