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IV. Chemical Identification
Methylene chloride (MC), also called dichloromethane (DCM) [Chemical
Abstracts Service Registry Number 75-09-2] is a halogenated aliphatic
hydrocarbon with a chemical formula of CH(2)Cl(2), a molecular weight of
84.9, a boiling point of 39.8 deg. C (104 deg. F) at 760 mm Hg, a specific
gravity of 1.3, a vapor density of 2.9 and a vapor pressure of 350 mm Hg at
20 deg. C (68 deg. F). Concentration of MC in saturated air at 25 deg. C
reaches 550,000 ppm. MC has low water solubility (1.3 gm per 100 gm of water
at 20 deg. C), an extensive oil and fat solubility, and a low flammability
potential. It is used as a flame suppressant in solvent mixtures (lower
explosive limit of 12% and upper explosive limit of 19%). It is a colorless
volatile liquid with a chloroform-like odor and its odor threshold varies
between 100 and 300 ppm. Contact with strong oxidizers, caustics and active
metal powder may cause explosions and fires. Decomposition products during
combustion or fire include phosgene, hydrogen chloride and carbon monoxide.
[62 FR 1494, January 10, 1997]
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