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Trifluorobromomethane

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General Description
    Synonyms: Bromotrifluoromethane; Fluorocarbon 1301; FreonŽ 13B1; Halocarbon 13B1; HalonŽ 1301; Monobromotrifluoromethane; Refrigerant 13B1; Trifluoromonobromomethane

    OSHA IMIS Code Number: 2500
    IMIS Name History: Trifluoromonobromomethane prior to 5/31/08

    Chemical Abstracts Service (CAS) Registry Number: 75-63-8

    NIOSH, Registry of Toxic Effects (RTECS) Identification Number: PA5425000

    Department of Transportation Regulation Number (49 CFR 172.101) and Guide: 1009 126 [27 KB, PDF]

    NIOSH Pocket Guide to Chemical Hazards, Trifluorobromomethane: chemical description, physical properties, potentially hazardous incompatibilities, and more
Exposure Limits
    OSHA Permissible Exposure Limit (PEL) for General Industry: 29 CFR 1910.1000 Z-1 Table -- 1000 ppm, 6100 mg/m3 TWA

    OSHA Permissible Exposure Limit (PEL) for Construction Industry: 29 CFR 1926.55 Appendix A -- 1000 ppm, 6100 mg/m3 TWA

    OSHA Permissible Exposure Limit (PEL) for Maritime: 29 CFR 1915.1000 Table Z-Shipyards -- 1000 ppm, 6100 mg/m3 TWA

    American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV): 1000 ppm, 6090 mg/m3 TWA

    National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL): 1000 ppm, 6100 mg/m3 TWA
Health Factors
    NIOSH Immediately Dangerous To Life or Health Concentration (IDLH): 40,000 ppm

    Potential symptoms: Dizziness; cardiac arrhythmias; liquid: frostbite

    Health Effects: Apparent low toxicity (HE19)

    Affected organs: Heart, CNS

    Literature Basis:
Monitoring Methods used by OSHA
    Laboratory Sampling/Analytical Method:

    • sampling media: Two Charcoal Tubes in series (First tube 400/200 mg sections, second tube 100/50 mg sections; both 20/40 mesh)
      analytical solvent: Methylene chloride
      alternate analytical solvent: Carbon Disulfide
      maximum volume: 1 Liter   maximum flow rate: 0.05 L/min
      current analytical method: Gas Chromatography; GC/FID
      method reference: NIOSH Analytical Method (NIOSH 1017) [21 KB, PDF]
      method classification: Fully Validated

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