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Chemical Sampling Information
o-Toluidine
 Field Definitions
 Analytical Methods
 Health Guidelines
General Description

NAME: o-Toluidine

SYNONYM(s): ortho-Aminotoluene; o-Methylaniline; 1-Methyl-1,2-amino-benzene; 2-Methylaniline

IMIS: 2475

CAS: 95-53-4

NIOSH: RTECS XU2975000; 83249

DOT: UN1708 Poison

DESCRIPTION:

Colorless to pale yellow liquid with a weak, aromatic odor.
MW: 107
BP: 391 F
VP: <1 mm
MP: -3 F

INCOM: Strong oxidizers

Exposure Limits

OSHA GENERAL INDUSTRY PEL: 5 ppm, 22 mg/m3 (Skin)

OSHA CONSTRUCTION INDUSTRY PEL: 5 ppm, 22 mg/m3 TWA (Skin)

ACGIH TLV: 2 ppm, 8.8 mg/m3 TWA (Skin); Appendix A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans)

NIOSH REL: Potential Carcinogen; lowest feasible concentration (Skin)

Health Factors

NTP: Suspect Human Carcinogen

IARC: Group 2B, possibly carcinogenic to humans

SYMPTOM(s): Anoxia; headaches; cyanosis; weakness, dizziness, drowsiness, micro hematuria; eye burns; dermatitis; (carcinogenic)

HEALTH EFFECTS: Methemoglobinemia (HE13); Acute systemic effects (HE4)

ORGAN: Blood, kidneys, liver, CVS, skin, eyes

Monitoring

PRIMARY SAMPLING/ANALYTICAL METHOD (SLC1):



MEDIA: Coated Glass Fiber Filters (37 mm) in 3 piece cassette. Coating is Sulfuric Acid.
MAX V: 100 Liters   MAX F: 1.0 L/min
ANL 1: Gas Chromatography; GC/ECD
REF: 2 (OSHA 73)
SAE: 0.09
CLASS: Fully Validated
NOTE: Filters may be obtained by OSHA personnel from SLTC.

SECONDARY SAMPLING/ANALYTICAL METHOD (SAM2):


DEVICE: Detector Tube COMPANY: Gastec
PART #: 181 RANGE: 2.5-35 ppm
CLASS: Mfg
DEVICE: Instrumentation COMPANY: Infrared Spectrophotometer
PART #: MIRAN 1A & 1B RANGE: 0.9 ppm @ 13.5 um
CLASS: Mfg

BULK METHOD:

Limit the amount of bulk submitted to one gram or one mL.


Revision Date: 01/19/1999
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