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Pentaerythritol (Total Dust) Chemical Sampling Information
Pentaerythritol (Total Dust)

General Description
    Synonyms: 2,2-bis(Hydroxymethyl)-1,3-propanediol; Methane tetramethylol; Monopentaerythritol; PE; Tetrahydroxymethylolmethane; Tetramethylolmethane

    OSHA IMIS Code Number: 1987

    Chemical Abstracts Service (CAS) Registry Number: 115-77-5

    NIOSH, Registry of Toxic Effects (RTECS) Identification Number: RZ2490000

    NIOSH Pocket Guide to Chemical Hazards, Pentaerythritol: chemical description, physical properties, potentially hazardous incompatibilities, and more
Exposure Limits
    OSHA Permissible Exposure Limit (PEL) for General Industry: 29 CFR 1910.1000 Z-1 Table -- 15 mg/m3 TWA

    OSHA Permissible Exposure Limit (PEL) for Maritime: 29 CFR 1915.1000 Table Z-Shipyards -- 15 mg/m3 TWA

    American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV): 10 mg/m3 TWA

    National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL): 10 mg/m3 TWA
Health Factors
    Potential symptoms: Irritation of eyes, respiratory system. INGES. ACUTE: In animals: stool softening, diarrhea; tremors, ataxia, loss of righting reflex.

    Health Effects: Nuisance particulate (HE19); LD50 (oral, guinea pig) 11.3 g/kg

    Affected organs: Eyes, respiratory system

    Notes: 1) Studies in rabbits indicated no skin irritation, but conjunctival instillation of a 50% aqueous suspension caused slight and transient eye irritation. 2) Pentaerythritol is excreted unchanged in the urine.

    Date Last Revised: 09/19/2005

    Literature Basis:
    • NIOSH Pocket Guide to Chemical Hazards: Pentaerythritol.
    • NIOSH: Toxicologic review of selected chemicals: Pentaerythritol.
    • Pohanish, R.P. (editor): Pentaerythritol. In, Sittig's Handbook of Toxic and Hazardous Chemicals and Carcinogens, Fourth Ed., Vol. 2. Norwich, NY: Noyes Publications, William Andrew Publishing, 2002, pp. 1804-1805.
Monitoring Methods used by OSHA
    Laboratory Sampling/Analytical Method:

    • sampling media: tared 37-mm diameter low-ash polyvinyl chloride filter
      maximum volume: 102 Liters   maximum flow rate: 1.7 L/min
      current analytical method: Gravimetric
      method reference: OSHA Analytical Method (OSHA PV2121)
      method classification: Partially Validated
      note: OSHA personnel can obtain tared sampling media from SLTC.
      note: If the net weight of the sample yields a concentration below the standard for the substance, SLTC will perform no further work on that sample. If the net weight corresponds to an amount greater than the standard, the sample may be analyzed for the appropriate material and the result reported as the substance.
      current elemental analysis method: Gas Chromatography; GC/FID
      method reference: OSHA SLTC In-House File
      method classification: Not Validated
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Page last updated: 04/06/2006

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