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alpha-Alumina (Respirable Fraction)

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General Description
    Synonyms: Aluminum Oxide (2:3); alpha-Aluminum Oxide; beta-Aluminum Oxide; gamma-Aluminum Oxide; Aluminum Sesquioxide

    OSHA IMIS Code Number: A201
    IMIS Name History: alpha-Alumina (Total Dust) from 7/17 to 9/1/89

    Chemical Abstracts Service (CAS) Registry Number: 1344-28-1

    NIOSH, Registry of Toxic Effects (RTECS) Identification Number: BD1200000

    NIOSH Pocket Guide to Chemical Hazards, alpha-Alumina: chemical description, physical properties, potentially hazardous incompatibilities, and more
Exposure Limits
    OSHA Permissible Exposure Limit (PEL) for General Industry: 29 CFR 1910.1000 Z-1 Table -- 5 mg/m3 TWA

    OSHA Permissible Exposure Limit (PEL) for Maritime: 29 CFR 1915.1000 Table Z-Shipyards -- 5 mg/m3 TWA

    American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV): 1 mg/m3 TWA; Respirable fraction; see Appendix C, paragraph C; Appendix A4 - Not Classifiable as a Human Carcinogen (Listed under Aluminum metal and Insoluble compounds)

    National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL): Appendix D - Substances With No Established RELs
Health Factors Monitoring Methods used by OSHA
    Laboratory Sampling/Analytical Method:

    Federal OSHA and OSHA State Plan personnel submitting samples to OSHA SLTC Laboratory for alpha-alumina analysis must use the tared gravimetric sampling media described immediately below.
    • sampling media: tared 37-mm diameter low-ash polyvinyl chloride filter preceded by 10 mm Nylon Cyclone
      maximum volume: 816 Liters
      minimum volume: 408 Liters flow rate: 1.7 L/min
      current analytical method: Gravimetric
      method reference: OSHA Analytical Method (OSHA PV2121)
      method classification: Partially Validated
      note: OSHA personnel can obtain tared sampling media from SLTC.
      note: If the net weight of the sample yields a concentration below the standard for the substance, SLTC will perform no further work on that sample. If the net weight corresponds to an amount greater than the standard, the sample may be analyzed for the appropriate element and the result reported as the substance.
      note: Refer to Chemical Sampling Information for “Aluminum (as Al) Metal” when sampling workplaces that have aluminum metal exposures (grinding, etc.).
      current elemental analysis method: Lithium Borate Fusion/AAS or Microwave Digestion/AAS
      method reference: OSHA Analytical Method (OSHA ID-109SG or OSHA ID-198SG)
      method classification: Partially Validated
      alternate analytical method: Inductively Coupled Argon Plasma; ICP/AES, ICP/MS
      note: Submit as a separate sample. When analysis of a compound is requested, an elemental analysis is performed and reported as the compound. The analytical method does not distinguish between dust and fume. The method does not distinguish between aluminum oxide and other aluminum compounds (e.g. aluminum phosphate, aluminum metal, etc.).
    Alternative Sampling/Analytical Method:
    • sampling media: Mixed Cellulose Ester Filter (MCEF) 0.8 µm preceded by 10 mm Nylon Cyclone
      maximum volume: 816 Liters
      minimum volume: 408 Liters flow rate: 1.7 L/min
      note: Refer to Chemical Sampling Information for “Aluminum (as Al) Metal” when sampling workplaces that have aluminum metal exposures (grinding, etc.).
      current elemental analysis method: Lithium Borate Fusion/AAS or Microwave Digestion/AAS
      method reference: OSHA Analytical Method (OSHA ID-109SG or OSHA ID-198SG)
      method classification: Partially Validated
      alternate analytical method: Inductively Coupled Argon Plasma; ICP/AES, ICP/MS
      note: Submit as a separate sample. When analysis of a compound is requested, an elemental analysis is performed and reported as the compound. The analytical method does not distinguish between dust and fume. The method also does not distinguish between aluminum oxide and other aluminum compounds (e.g. aluminum phosphate, aluminum metal, etc.).

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