Methodologies


Brief OSHA Comparisons of Analytical Methods for Crystalline Silica (Table).

XRD

IR or FTIR

Chemical or Colorometric

Other, e.g., Thermal Analysis

Universal Coal or specific evaluated matrix Specific evaluated matrix Thermal analysis not well suited for air samples.
Non-destructive Non-destructive to analyte destructive to matrix Destructive to analyte and matrix. Generally destructive towards matrix.
MSDS often useful MSDS needed for non-evaluated matrices. MSDS needed MSDS needed
Type or description of operation Type or description of operation Type or description of operation Type or description of operation
List specific crystalline interferences known to be present at worksite List chemical interferences known to be present at worksite List crystalline and chemical interferences known to be present at worksite. Interferences include ionic fluorides, e.g., CaF2 No likely interferences except perhaps alkaline materials.
Air volume and Sample mass Air volume and Sample mass Air volume and Sample mass (Bulks only)
Confirmation readily available. Confirmation possible. No confirmation generally available. Bulks may be confirmed by microscopy. No additional confirmation needed; very specific to quartz.
Can analyze quartz, cristobalite, and tridymite in diverse respirable dust matrices. Can analyze quartz, cristobalite, and tridymite in specific respirable dust matrices. Can analyze but not distinguish quartz, cristobalite, and tridymite in many respirable dust matrices. Can analyze quartz in many bulk matrices.

Last Updated on March 3, 1997 by Mike C. Rose